Dual Immobilization of SnO Nanoparticles by N-Doped Carbon and TiO for High-Performance Lithium-Ion Battery Anodes.

The grain aggregation engendered kinetics failure is regarded as the main reason for the electrochemical decay of nanosized anode materials. Herein, we proposed a dual immobilization strategy to suppress the migration and aggregation of SnO nanoparticles and corresponding lithiation products through constructing SnO/TiO@PC composites. The N-doped carbon could anchor the tin oxide particles and inhibit their aggregation during the preparation process, leading to a uniform distribution of ultrafine SnO nanoparticles in the matrix. Meanwhile, the incorporated TiO component works as parclose to suppress the migration and coarsening of SnO and corresponding lithiation products. In addition, the N-doped carbon and TiO/LiTiO can significantly improve the electrical and ionic conductivities of the composites, enabling a good diffusion and charge-transfer dynamics. Owing to the dual immobilization from the "synergistic effect" of N-doped carbon and the "parclose effect" of TiO, the conversion reaction of SnO remains fully reversible throughout the cycling. Thereby, the composites exhibit excellent cycling performance in half cells and can be fully utilized in full cells. This work may provide an inspiration for the rational design of tin-based anodes for high-performance lithium-ion batteries.