Sepulveda L, Lissi E, Quina F
Department of Chemistry, Faculty of Sciences, University of Chile, Santiago.
Adv Colloid Interface Sci. 1986 Jun;25(1):1-57. doi: 10.1016/0001-8686(86)80001-x.
The interactions of neutral molecules with ionic micelles are analyzed. The cell and mass action models are presented in order to provide a semi-quantitative description of the solubilization process. Both approaches are discussed from a thermodynamic and kinetic point of view and the different definitions of solute incorporation constants are also discussed and compared. An extensive compilation of standard free energies of transfer from water to micelles is provided and the basis of the employed methods to obtain them is presented. Several aspects of the solubilization process such as its dynamics, the effect of additives, the probe microenvironment and its dependence with the solute mean occupation number are reviewed and critically discussed. The effect of solute incorporation upon the micelle shape and size is also briefly reviewed.
分析了中性分子与离子型胶束的相互作用。提出了细胞模型和质量作用模型，以便对增溶过程进行半定量描述。从热力学和动力学角度讨论了这两种方法，并对溶质掺入常数的不同定义进行了讨论和比较。提供了从水到胶束转移的标准自由能的广泛汇编，并介绍了获得这些自由能所采用方法的基础。对增溶过程的几个方面进行了综述和批判性讨论，如增溶过程的动力学、添加剂的影响、探针微环境及其与溶质平均占据数的关系。还简要回顾了溶质掺入对胶束形状和大小的影响。
