Tallon Jeffery L, Loram John W
Robinson Research Institute, and MacDiarmid Institute for Advanced Materials and Nanotechnology, Victoria University of Wellington, P.O. Box 33436, Lower Hutt, 5046 New Zealand.
Cavendish Laboratory, Cambridge University, Cambridge, CB3 0HE UK.
Sci Rep. 2020 Dec 18;10(1):22288. doi: 10.1038/s41598-020-79017-3.
The cuprate superconductor [Formula: see text], in comparison with most other cuprates, has a stable stoichiometry, is largely free of defects and may be regarded as the canonical underdoped cuprate, displaying marked pseudogap behaviour and an associated distinct weakening of superconducting properties. This cuprate 'pseudogap' manifests as a partial gap in the electronic density of states at the Fermi level and is observed in most spectroscopic properties. After several decades of intensive study it is widely believed that the pseudogap closes, mean-field like, near a characteristic temperature, [Formula: see text], which rises with decreasing hole concentration, p. Here, we report extensive field-dependent electronic specific heat studies on [Formula: see text] up to an unprecedented 400 K and show unequivocally that the pseudogap never closes, remaining open to at least 400 K where [Formula: see text] is typically presumed to be about 150 K. We show from the NMR Knight shift and the electronic entropy that the Wilson ratio is numerically consistent with a weakly-interacting Fermion system for the near-nodal states. And, from the field-dependent specific heat, we characterise the impact of fluctuations and impurity scattering on the thermodynamic properties.
与大多数其他铜酸盐相比,铜酸盐超导体[化学式:见正文]具有稳定的化学计量比,基本没有缺陷,可被视为典型的欠掺杂铜酸盐,表现出明显的赝能隙行为以及超导性能的相关明显减弱。这种铜酸盐“赝能隙”表现为费米能级处电子态密度的部分能隙,并且在大多数光谱性质中都能观察到。经过几十年的深入研究,人们普遍认为赝能隙在一个特征温度[化学式:见正文]附近类似平均场的方式闭合,该温度随着空穴浓度p的降低而升高。在此,我们报告了对[化学式:见正文]进行的高达前所未有的400 K的广泛的场依赖电子比热研究,明确表明赝能隙从未闭合,至少在400 K时仍保持开放,而通常认为[化学式:见正文]约为150 K。我们从核磁共振奈特位移和电子熵表明,对于近节点态,威尔逊比率在数值上与弱相互作用费米子系统一致。并且,从场依赖比热,我们表征了涨落和杂质散射对热力学性质的影响。