Oksdath-Mansilla Gabriela, Kucera Renata L, Chalker Justin M, Raston Colin L
INFIQC-CONICET-UNC, Dpto. de Química Orgánica, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, Córdoba, Argentina and Institute for Nanoscale Science and Technology, College of Science and Engineering, Flinders University, Bedford Park, South Australia, 5042, Australia.
Institute for Nanoscale Science and Technology, College of Science and Engineering, Flinders University, Bedford Park, South Australia, 5042, Australia.
Chem Commun (Camb). 2021 Jan 21;57(5):659-662. doi: 10.1039/d0cc04401f.
The Vortex Fluidic Device is a flow reactor that processes reactions in thin films. Running the metal-free azide-alkyne cycloaddition in this reactor revealed a dramatic enhancement of the "on water" effect. For the copper-catalyzed azide-alkyne cycloaddition, stainless steel or copper jet feeds were effective reservoirs of active copper catalyst.
涡旋流体装置是一种在薄膜中进行反应处理的流动反应器。在该反应器中进行无金属叠氮化物-炔烃环加成反应时,“水相”效应显著增强。对于铜催化的叠氮化物-炔烃环加成反应,不锈钢或铜喷射进料是活性铜催化剂的有效储存器。