Zhang Xia, Liu Bin, Xiao Bo-Lin, Wang Jia, Wan Da
College of Environment and Ecology, Chongqing University, Chongqing 400044, China.
Huan Jing Ke Xue. 2020 Dec 8;41(12):5288-5294. doi: 10.13227/j.hjkx.202001142.
Pollution characteristics and risk of heavy metals in atmospheric deposition in core urban areas of Chongqing were investigated for one year from December 2017 to November 2018.Six functional zones:suburb, education area, residential area, commercial area, transportation hub, and industrial-residential area in Chongqing were selected for monthly atmospheric deposition collection. Concentrations of Cd, Cr, Ni, and Pb were analyzed using AAS. The potential ecological risk index and geoaccumulation index were used to evaluate the heavy metals pollution. Results show that the concentrations of Cd, Cr, Ni, and Pb in the atmospheric deposition were 1.59, 72.68, 20.99, and 101.17 mg·kg, respectively, and their annual deposition fluxes were 0.39, 8.04, 2.41, and 10.41 mg·(m·a), respectively. Concentrations of heavy metals in autumn were significantly higher than those in the other three seasons, especially for Cd, and their deposition fluxes in winter were lowest. The potential ecological risk index of Cd was biggest, achieving a very high ecological hazard level, while the ecological risk of Cd and Pb in industrial-residential area was highest, and that of Cr and Ni, respectively, were highest in transportation hub and residential area. The geoaccumulation index indicated that the pollution of Cd was the highest, and that of Cr, Ni, and Pb was very low. The pollution in industrial-residential area and transportation hub was high, while that in the suburb was relatively low.
2017年12月至2018年11月,对重庆核心城区大气沉降中重金属的污染特征和风险进行了为期一年的调查。选取了重庆的六个功能区:郊区、教育区、居民区、商业区、交通枢纽和工业居住区,每月收集大气沉降物。采用原子吸收光谱法分析镉、铬、镍和铅的浓度。利用潜在生态风险指数和地累积指数对重金属污染进行评价。结果表明,大气沉降中镉、铬、镍和铅的浓度分别为1.59、72.68、20.99和101.17mg·kg,其年沉降通量分别为0.39、8.04、2.41和10.41mg·(m²·a)。秋季重金属浓度显著高于其他三个季节,尤其是镉,其冬季沉降通量最低。镉的潜在生态风险指数最大,达到很高的生态危害水平,而工业居住区镉和铅的生态风险最高,铬和镍的生态风险分别在交通枢纽和居民区最高。地累积指数表明,镉的污染最高,铬、镍和铅的污染很低。工业居住区和交通枢纽的污染较高,而郊区的污染相对较低。