School of Chemical Sciences, Universiti Sains Malaysia (USM), Gelugor 11800, Penang, Malaysia.
School of Pharmacy and Biomolecular Sciences, University of Brighton, Brighton BN2 4GJ, UK.
Molecules. 2020 Dec 23;26(1):21. doi: 10.3390/molecules26010021.
The development of low-cost electrode devices from conductive materials has recently attracted considerable attention as a sustainable means to replace the existing commercially available electrodes. In this study, two different electrode surfaces (surfaces 1 and 2, denoted as S1 and S2) were fabricated from chocolate wrapping aluminum foils. Energy dispersive X-Ray (EDX) and field emission scanning electron microscopy (FESEM) were used to investigate the elemental composition and surface morphology of the prepared electrodes. Meanwhile, cyclic voltammetry (CV), chronoamperometry, electrochemical impedance spectroscopy (EIS), and differential pulse voltammetry (DPV) were used to assess the electrical conductivities and the electrochemical activities of the prepared electrodes. It was found that the fabricated electrode strips, particularly the S1 electrode, showed good electrochemical responses and conductivity properties in phosphate buffer (PB) solutions. Interestingly, both of the electrodes can respond to the ruthenium hexamine (Ruhex) redox species. The fundamental results presented from this study indicate that this electrode material can be an inexpensive alternative for the electrode substrate. Overall, our findings indicate that electrodes made from chocolate wrapping materials have promise as electrochemical sensors and can be utilized in various applications.
从导电材料开发低成本电极器件最近引起了相当大的关注,因为它是一种可持续的方法,可以替代现有的市售电极。在这项研究中,两种不同的电极表面(表面 1 和 2,分别表示为 S1 和 S2)是由巧克力包装铝箔制成的。使用能量色散 X 射线(EDX)和场发射扫描电子显微镜(FESEM)来研究制备电极的元素组成和表面形态。同时,使用循环伏安法(CV)、计时安培法、电化学阻抗谱(EIS)和差分脉冲伏安法(DPV)来评估制备电极的电导率和电化学活性。结果发现,所制备的电极条,特别是 S1 电极,在磷酸盐缓冲液(PB)溶液中表现出良好的电化学响应和电导率性能。有趣的是,两个电极都可以响应钌六胺(Ruhex)氧化还原物质。这项研究的基本结果表明,这种电极材料可以作为廉价的电极衬底的替代品。总的来说,我们的研究结果表明,由巧克力包装材料制成的电极具有作为电化学传感器的潜力,并可以应用于各种应用。