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超宽窗口中含InGaAs量子阱异质结构的选择性区域外延过程中的表面纳米结构化

Surface Nanostructuring during Selective Area Epitaxy of Heterostructures with InGaAs QWs in the Ultra-Wide Windows.

作者信息

Shamakhov Viktor, Nikolaev Dmitriy, Slipchenko Sergey, Fomin Evgenii, Smirnov Alexander, Eliseyev Ilya, Pikhtin Nikita, Kop Ev Peter

机构信息

Ioffe Institute, 26 Politekhnicheskaya, St Petersburg 194021, Russia.

Elfolum Ltd., 26 Politekhnicheskaya, St Petersburg 194021, Russia.

出版信息

Nanomaterials (Basel). 2020 Dec 23;11(1):11. doi: 10.3390/nano11010011.

Abstract

Selective area epitaxy (SAE) is widely used in photonic integrated circuits, but there is little information on the use of this technique for the growth of heterostructures in ultra-wide windows. Samples of heterostructures with InGaAs quantum wells (QWs) on GaAs (100) substrates with a pattern of alternating stripes (100-μm-wide SiO mask/100-μm-wide window) were grown using metalorganic chemical vapour deposition (MOCVD). It was found that due to a local change in the growth rate of InGaAs QW in the window, the photoluminescence (PL) spectra measured from the edge to the center of the window exhibited maximum blueshifts of 14 and 19 meV at temperatures of 80 K and 300 K, respectively. Using atomic force microscopy, we have demonstrated that the surface morphologies of structures grown using standard epitaxy or SAE under identical MOCVD growth conditions correspond to a step flow growth with a step height of ~1.5 ML or a step bunching growth mode, respectively. In the structures grown with the use of SAE, a strong variation in the surface morphology in an ultra-wide window from its center to the edge was revealed, which is explained by a change in the local misorientation of the layer due to a local change in the growth rate over the width of the window.

摘要

选择性区域外延(SAE)在光子集成电路中被广泛应用,但关于该技术在超宽窗口中生长异质结构的应用信息却很少。使用金属有机化学气相沉积(MOCVD)在具有交替条纹图案(100μm宽的SiO掩膜/100μm宽的窗口)的GaAs(100)衬底上生长了带有InGaAs量子阱(QW)的异质结构样品。结果发现,由于窗口中InGaAs QW生长速率的局部变化,在80K和300K温度下,从窗口边缘到中心测量的光致发光(PL)光谱分别呈现出最大14和19meV的蓝移。通过原子力显微镜,我们证明了在相同的MOCVD生长条件下,使用标准外延或SAE生长的结构的表面形貌分别对应于台阶高度约为1.5 ML的台阶流生长或台阶聚束生长模式。在使用SAE生长的结构中,揭示了超宽窗口从中心到边缘表面形貌的强烈变化,这是由于窗口宽度上生长速率的局部变化导致层的局部取向差发生变化所致。

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