Investigating low salinity waterflooding via glass micromodels with triangular pore-throat architectures.

Glass micromodels have been extensively used to simulate and investigate crude oil, brine, and surface interactions due to their homogeneous wettability, rigidity, and ability to precisely capture a reservoir's areal heterogeneity. Most micromodels are fabricated via two-dimensional patterning, implying that feature depths are constant despite varying width, which sub-optimally describes a three-dimensional porous architecture. We have successfully fabricated micromodels with arbitrary triangular cross sections via femtosecond pulsed laser direct writing resulting in depth-dependent channel width. As such, we have achieved arbitrary geometric control over device fabrication and thus a more accurate recapitulation of a geological porous media. With this fabrication technique, we are now able to directly observe pore-level, depth-dependent multiphase flow phenomena. This platform was used to study the low salinity effect (LSE) by simulating waterflooding processes using various brine solutions that differ in cation type and salinity. Patterned pore-throat structures were created to investigate displacement behavior during waterflooding. Real-time monitoring of the displacement processes, combined with a comparison of the brine chemistry before and after waterflooding provides an insight into realistic interactions occurring between crude oil and brine. The results indicate that produced emulsions were prone to coalesce in the presence of lower salinity brine. Combined with previous work, the LSE was interpreted as favored coalescence and resisted breakup that resulting in a more continuous aqueous phase during waterflooding therefore improving the displacement efficiency.