Surface functionalized highly porous date seed derived activated carbon and MoS nanocomposites for hydrogenation of CO into formic acid.

In recent years, substantial progress has been made towards developing effective catalysts for the hydrogenation of CO into fuels. However, the quest for a robust catalyst with high activity and stability still remains challenging. In this study, we present a cost-effective catalyst composed of MoS nanosheets and functionalized porous date seed-derived activated carbon (f-DSAC) for hydrogenation of CO into formic acid (FA). As-fabricated MoS/f-DSAC catalysts were characterized by FE-SEM, XRD, Raman, FT-IR, BET, and CO-TPD analyses. At first, bicarbonate (HCO) was successfully converted into FA with a high yield of 88% at 200 °C for 180 min under 10 bar H atmosphere. A possible reaction pathway for the conversion of HCO into FA is postulated. The catalyst has demonstrated high activity and long-term stability over five consecutive cycles. Additionally, MoS/f-DSAC catalyst was effectively used for the conversion of gaseous CO into FA at 200 °C under 20 bar (CO/H = 1:1) over 15 h. The catalyst exhibited a remarkable TOF of 510 h with very low activation energy of 12 kJ mol, thus enhancing the catalytic conversion rate of CO into FA. Thus, this work demonstrates the MoS/f-DSAC nanohybrid system as an efficient non-noble catalyst for converting CO into fuels.