Pandey Animesh, Yadav Reena, Kaur Mandeep, Singh Preetam, Gupta Anurag, Husale Sudhir
Academy of Scientific and Innovative Research (AcSIR), Council of Scientific and Industrial Research, National Physical Laboratory, Dr. K. S Krishnan Road, New Delhi, 110012, India.
Council of Scientific and Industrial Research, National Physical Laboratory, Dr. K. S Krishnan Road, New Delhi, 110012, India.
Sci Rep. 2021 Jan 12;11(1):832. doi: 10.1038/s41598-020-80738-8.
Topological insulators (TIs) possess exciting nonlinear optical properties due to presence of metallic surface states with the Dirac fermions and are predicted as a promising material for broadspectral phodotection ranging from UV (ultraviolet) to deep IR (infrared) or terahertz range. The recent experimental reports demonstrating nonlinear optical properties are mostly carried out on non-flexible substrates and there is a huge demand for the fabrication of high performing flexible optoelectronic devices using new exotic materials due to their potential applications in wearable devices, communications, sensors, imaging etc. Here first time we integrate the thin films of TIs (BiTe) with the flexible PET (polyethylene terephthalate) substrate and report the strong light absorption properties in these devices. Owing to small band gap material, evolving bulk and gapless surface state conduction, we observe high responsivity and detectivity at NIR (near infrared) wavelengths (39 A/W, 6.1 × 10 Jones for 1064 nm and 58 A/W, 6.1 × 10 Jones for 1550 nm). TIs based flexible devices show that photocurrent is linearly dependent on the incident laser power and applied bias voltage. Devices also show very fast response and decay times. Thus we believe that the superior optoelectronic properties reported here pave the way for making TIs based flexible optoelectronic devices.
拓扑绝缘体(TIs)由于存在具有狄拉克费米子的金属表面态而具有令人兴奋的非线性光学特性,并且被预测为一种有前途的材料,可用于从紫外(UV)到深红外(IR)或太赫兹范围的广谱光电探测。最近关于非线性光学特性的实验报告大多是在非柔性衬底上进行的,由于其在可穿戴设备、通信、传感器、成像等方面的潜在应用,对使用新型奇异材料制造高性能柔性光电器件有巨大需求。在此,我们首次将拓扑绝缘体(BiTe)薄膜与柔性聚对苯二甲酸乙二醇酯(PET)衬底集成在一起,并报告了这些器件中的强光吸收特性。由于其小带隙材料、不断演变的体相和无隙表面态传导,我们在近红外(NIR)波长(1064nm时为39 A/W,6.1×10琼斯;1550nm时为58 A/W,6.1×10琼斯)观察到了高响应度和探测率。基于拓扑绝缘体的柔性器件表明,光电流与入射激光功率和施加的偏置电压呈线性相关。器件还显示出非常快的响应和衰减时间。因此,我们相信这里报道的优异光电器件特性为制造基于拓扑绝缘体的柔性光电器件铺平了道路。