• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

煅烧温度对生物提取物介导的二氧化钛纳米粒子性能和应用的影响。

Effect of calcination temperature on the properties and applications of bio extract mediated titania nano particles.

机构信息

Department of Chemistry, RMK College of Engineering and Technology, Chennai, 601206, India.

Anna University, Chennai, 600025, India.

出版信息

Sci Rep. 2021 Jan 18;11(1):1734. doi: 10.1038/s41598-021-80997-z.

DOI:10.1038/s41598-021-80997-z
PMID:33462273
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7814144/
Abstract

In order to deal with the arising environmental issues across the globe at present nano particles with unique properties laid a benchmark in the name of nano catalysis. In this work the significance of calcination temperature on the thermal, electronic, structural and surface properties of a nano catalyst produced by sol-gel method using ultrasonic radiation against the disposal of toxic textile pollutants is studied in detail. The extract of tea leaves has been used as a bio-template during the synthesis to revise the crystallite size, surface area, optical absorption potential, and rate of agglomeration of nano sized grains by regulating their physico-chemical and surface properties. The influence of calcination in the transformation of single phased anatase titania to mixed phase anatase-rutile titania and the corresponding outcome in its photocatalytic activity employed in water treatment applications have been verified. The nano catalyst obtained is characterized by X-ray diffraction (XRD), Scanning electron microscopy (SEM), Transition electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), Thermo gravimetric analysis (TGA), Brunaueur Emmett Teller (BET) analysis, UV-Vis diffused reflectance spectroscopy (DRS-UV-Vis) etc. The mesoporosity of the particle was examined using Barrett Joyner Halenda (BJH) model. The enhanced photo catalytic efficiency (about 97.7%) of templated nano titania due to calcination is verified against Congo red, a textile dye under optimized conditions. The nano catalyst produced can be easily separated, recycled to support its economic feasibility.

摘要

为了解决目前全球出现的环境问题，具有独特性质的纳米粒子以纳米催化的名义成为了一个基准。在这项工作中，详细研究了通过溶胶-凝胶法使用超声辐射制备的纳米催化剂在热、电子、结构和表面性能方面的煅烧温度对其处理有毒纺织污染物的影响。在合成过程中，使用茶叶提取物作为生物模板，通过调节纳米颗粒的物理化学和表面性质，来修正其晶粒尺寸、比表面积、光吸收潜力和团聚率。验证了煅烧对单斜相锐钛矿向混合相锐钛矿-金红石钛的转变以及其在水处理应用中的光催化活性的影响。通过 X 射线衍射 (XRD)、扫描电子显微镜 (SEM)、透射电子显微镜 (TEM)、傅里叶变换红外光谱 (FT-IR)、热重分析 (TGA)、Brunaueur Emmett Teller (BET)分析、紫外可见漫反射光谱 (DRS-UV-Vis) 等方法对纳米催化剂进行了表征。使用 Barrett Joyner Halenda (BJH) 模型检查了颗粒的中孔性。在优化条件下，通过煅烧制备的模板纳米二氧化钛对刚果红（一种纺织染料）的光催化效率（约 97.7%）得到了验证。所制备的纳米催化剂易于分离和回收，支持其经济可行性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/c6e4e49daea2/41598_2021_80997_Fig23_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/e0be854af2cd/41598_2021_80997_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/56f946dfec91/41598_2021_80997_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/9d6d704df5ca/41598_2021_80997_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/5883e4536fd9/41598_2021_80997_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/f0de83047bc9/41598_2021_80997_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/dd9c5407c156/41598_2021_80997_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/32a6744fbe45/41598_2021_80997_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/5621ec26e7db/41598_2021_80997_Fig8_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/11f7f8d32c6a/41598_2021_80997_Fig9_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/47d94a6f31c6/41598_2021_80997_Fig10_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/a143bc2b26f8/41598_2021_80997_Fig11_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/50fd110f8215/41598_2021_80997_Fig12_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/201cfd5a434b/41598_2021_80997_Fig13_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/cca1cf7612bc/41598_2021_80997_Fig14_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/77da00ecfdf7/41598_2021_80997_Fig15_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/68e8418c5f04/41598_2021_80997_Sch1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/1bc4c04df051/41598_2021_80997_Fig16_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/5db1e97e451c/41598_2021_80997_Fig17_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/878271049d34/41598_2021_80997_Fig18_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/840f100e03ae/41598_2021_80997_Fig19_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/378b6fef7536/41598_2021_80997_Fig20_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/ccd3a38be8f1/41598_2021_80997_Fig21_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/cd23d697a867/41598_2021_80997_Fig22_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/c6e4e49daea2/41598_2021_80997_Fig23_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/e0be854af2cd/41598_2021_80997_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/56f946dfec91/41598_2021_80997_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/9d6d704df5ca/41598_2021_80997_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/5883e4536fd9/41598_2021_80997_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/f0de83047bc9/41598_2021_80997_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/dd9c5407c156/41598_2021_80997_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/32a6744fbe45/41598_2021_80997_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/5621ec26e7db/41598_2021_80997_Fig8_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/11f7f8d32c6a/41598_2021_80997_Fig9_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/47d94a6f31c6/41598_2021_80997_Fig10_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/a143bc2b26f8/41598_2021_80997_Fig11_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/50fd110f8215/41598_2021_80997_Fig12_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/201cfd5a434b/41598_2021_80997_Fig13_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/cca1cf7612bc/41598_2021_80997_Fig14_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/77da00ecfdf7/41598_2021_80997_Fig15_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/68e8418c5f04/41598_2021_80997_Sch1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/1bc4c04df051/41598_2021_80997_Fig16_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/5db1e97e451c/41598_2021_80997_Fig17_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/878271049d34/41598_2021_80997_Fig18_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/840f100e03ae/41598_2021_80997_Fig19_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/378b6fef7536/41598_2021_80997_Fig20_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/ccd3a38be8f1/41598_2021_80997_Fig21_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/cd23d697a867/41598_2021_80997_Fig22_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5a8/7814144/c6e4e49daea2/41598_2021_80997_Fig23_HTML.jpg

相似文献

1
Effect of calcination temperature on the properties and applications of bio extract mediated titania nano particles.煅烧温度对生物提取物介导的二氧化钛纳米粒子性能和应用的影响。
Sci Rep. 2021 Jan 18;11(1):1734. doi: 10.1038/s41598-021-80997-z.
2
Recent advances in the use of graphene-family nanoadsorbents for removal of toxic pollutants from wastewater.石墨烯基纳米吸附剂在去除废水中有毒污染物方面的最新进展。
Adv Colloid Interface Sci. 2014 Feb;204:35-56. doi: 10.1016/j.cis.2013.12.005. Epub 2013 Dec 26.
3
Synthesis of highly active sulfate-promoted rutile titania nanoparticles with a response to visible light.具有可见光响应的高活性硫酸盐促进金红石型二氧化钛纳米颗粒的合成
J Phys Chem B. 2005 Mar 31;109(12):5554-60. doi: 10.1021/jp045676l.
4
Photocatalytic efficiency of FeO/TiO for the degradation of typical dyes in textile industries: Effects of calcination temperature and UV-assisted thermal synthesis.FeO/TiO对纺织工业中典型染料的光催化降解效率：煅烧温度和紫外辅助热合成的影响
J Environ Manage. 2017 Jul 1;196:487-498. doi: 10.1016/j.jenvman.2017.03.030. Epub 2017 Mar 24.
5
Green Synthesis of NiO-SnO Nanocomposite and Effect of Calcination Temperature on Its Physicochemical Properties: Impact on the Photocatalytic Degradation of Methyl Orange.NiO-SnO 纳米复合材料的绿色合成及其煅烧温度对其物理化学性质的影响：对甲基橙光催化降解的影响。
Molecules. 2022 Dec 1;27(23):8420. doi: 10.3390/molecules27238420.
6
Efficient photocatalytic degradation of organic pollutants by magnetically recoverable nitrogen-doped TiO2 nanocomposite photocatalysts under visible light irradiation.磁性可回收的氮掺杂TiO₂纳米复合光催化剂在可见光照射下对有机污染物的高效光催化降解
Environ Sci Pollut Res Int. 2015 Dec;22(23):18859-73. doi: 10.1007/s11356-015-5032-3. Epub 2015 Jul 24.
7
Photocatalytic Decolorization and Biocidal Applications of Nonmetal Doped TiO: Isotherm, Kinetic Modeling and In Silico Molecular Docking Studies.非金属掺杂 TiO 的光催化脱色和杀菌应用：等温线、动力学模型和计算机分子对接研究。
Molecules. 2020 Sep 29;25(19):4468. doi: 10.3390/molecules25194468.
8
Visible light responsive sulfated rare earth doped TiO(2)@fumed SiO(2) composites with mesoporosity: enhanced photocatalytic activity for methyl orange degradation.具有中孔结构的可见光敏化硫酸化稀土掺杂 TiO(2)@气相 SiO(2)复合材料：增强对甲基橙降解的光催化活性。
J Hazard Mater. 2014 Feb 28;267:88-97. doi: 10.1016/j.jhazmat.2013.12.038. Epub 2013 Dec 27.
9
Controlling the growth of nanosized titania polymer gelation for photocatalytic applications.控制用于光催化应用的纳米二氧化钛聚合物凝胶化的生长
RSC Adv. 2020 May 21;10(33):19443-19453. doi: 10.1039/d0ra03312j. eCollection 2020 May 20.
10
Facile Formation of Anatase/Rutile TiO Nanocomposites with Enhanced Photocatalytic Activity.锐钛矿/金红石 TiO 纳米复合材料的简便制备及其增强的光催化活性。
Molecules. 2019 Aug 19;24(16):2996. doi: 10.3390/molecules24162996.

引用本文的文献

1
Enhanced photocatalytic degradation of 2,4-dichlorophenoxyacetic acid from freshwater and industrial wastewater using TiO-CuO-clay soil nanocomposites.使用TiO-CuO-黏土纳米复合材料增强对淡水和工业废水中2,4-二氯苯氧乙酸的光催化降解。
Sci Rep. 2025 Aug 25;15(1):31198. doi: 10.1038/s41598-025-11814-0.
2
pH-responsive nanocapsules loaded with 5-fluorouracil-coated green-synthesized CuO-ZnO NPs for enhanced anticancer activity against HeLa cells.负载5-氟尿嘧啶的pH响应性纳米胶囊包裹绿色合成的CuO-ZnO纳米颗粒，用于增强对HeLa细胞的抗癌活性。
Med Oncol. 2025 Jun 30;42(8):300. doi: 10.1007/s12032-025-02847-6.
3
Enhanced photocatalytic performance of non-stoichiometric WO nanocrystals via near-infrared localized surface plasmon resonance.

本文引用的文献

1
Rapid biosynthesis and characterization of silver nanoparticles from the leaf extract of Tropaeolum majus L. and its enhanced in-vitro antibacterial, antifungal, antioxidant and anticancer properties.从金莲花叶提取物中快速生物合成和表征银纳米粒子及其增强的体外抗菌、抗真菌、抗氧化和抗癌特性。
J Photochem Photobiol B. 2019 Feb;191:65-74. doi: 10.1016/j.jphotobiol.2018.12.010. Epub 2018 Dec 14.
2
A facile solvothermal method to produce ZnS quantum dots-decorated graphene nanosheets with superior photoactivity.一种简便的溶剂热法制备具有优异光催化活性的 ZnS 量子点修饰石墨烯纳米片的方法。
Nanotechnology. 2013 Sep 20;24(37):375601. doi: 10.1088/0957-4484/24/37/375601. Epub 2013 Aug 21.
3
通过近红外局域表面等离子体共振增强非化学计量比WO纳米晶体的光催化性能。
Sci Rep. 2025 Apr 26;15(1):14624. doi: 10.1038/s41598-025-99138-x.
4
Comprehensive insights into phosphorus solubility and organic matter's impact on black phosphate leaching.关于磷溶解度以及有机质对黑磷浸出影响的综合见解。
Sci Rep. 2024 Aug 19;14(1):19159. doi: 10.1038/s41598-024-69399-z.
5
Phase variation of manganese oxide in the MnO@ZnO nanocomposite with calcination temperature and its effect on structural and biological activities.煅烧温度对 MnO@ZnO 纳米复合材料中氧化锰的相变化及其对结构和生物活性的影响。
Sci Rep. 2023 Dec 6;13(1):21542. doi: 10.1038/s41598-023-48695-0.
6
Metal organic framework derived NiO nanoparticles for application as a hole transport layer in perovskite solar cells.用于钙钛矿太阳能电池中作为空穴传输层的金属有机框架衍生的NiO纳米颗粒。
RSC Adv. 2023 Apr 27;13(19):12781-12791. doi: 10.1039/d3ra02181e. eCollection 2023 Apr 24.
7
Scavenging of Organic Pollutant and Fuel Generation through Cost-Effective and Abundantly Accessible Rust: A Theoretical Support with DFT Simulations.通过经济高效且易于获取的铁锈清除有机污染物并产生燃料：基于密度泛函理论模拟的理论支持
Materials (Basel). 2022 Dec 23;16(1):142. doi: 10.3390/ma16010142.
8
Growth inhibition of bacterial pathogens by photo-catalyst process of nano-alloys FeCuNi doped TiO under ultraviolet irradiation.紫外光照射下纳米合金FeCuNi掺杂TiO₂光催化过程对细菌病原体的生长抑制作用
Heliyon. 2022 Sep 13;8(9):e10611. doi: 10.1016/j.heliyon.2022.e10611. eCollection 2022 Sep.
9
Green Synthesis and Investigation of Surface Effects of α-FeO@TiO Nanocomposites by Impedance Spectroscopy.α-FeO@TiO纳米复合材料的绿色合成及阻抗谱对其表面效应的研究
Materials (Basel). 2022 Aug 21;15(16):5768. doi: 10.3390/ma15165768.
10
The physical and optical investigations of the tannic acid functionalised Cu-based oxide nanostructures.单宁酸功能化 Cu 基氧化物纳米结构的物理和光学研究。
Sci Rep. 2022 Jun 14;12(1):9909. doi: 10.1038/s41598-022-14281-z.
Brookite versus anatase TiO2 photocatalysts: phase transformations and photocatalytic activities.
锐钛矿型 TiO2 与板钛矿型 TiO2 光催化剂：相变与光催化活性。
Photochem Photobiol Sci. 2013 Apr;12(4):602-9. doi: 10.1039/c2pp25217a.
4
Photocatalytic decolorization and degradation of Congo Red on innovative crosslinked chitosan/nano-CdS composite catalyst under visible light irradiation.可见光照射下新型交联壳聚糖/纳米硫化镉复合催化剂对刚果红的光催化脱色及降解
J Hazard Mater. 2009 Sep 30;169(1-3):933-40. doi: 10.1016/j.jhazmat.2009.04.037. Epub 2009 Apr 18.
5
Factors affecting the levels of tea polyphenols and caffeine in tea leaves.影响茶叶中茶多酚和咖啡因含量的因素。
J Agric Food Chem. 2003 Mar 26;51(7):1864-73. doi: 10.1021/jf021066b.
6
Visible-light photocatalysis in nitrogen-doped titanium oxides.氮掺杂二氧化钛中的可见光光催化作用
Science. 2001 Jul 13;293(5528):269-71. doi: 10.1126/science.1061051.