• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

使用环境友好型工艺去除水中新兴污染物：光催化剂的制备、表征、中间体鉴定及毒性评估。

Removal of Emerging Pollutants from Water Using Environmentally Friendly Processes: Photocatalysts Preparation, Characterization, Intermediates Identification and Toxicity Assessment.

作者信息

Finčur Nina, Sfîrloagă Paula, Putnik Predrag, Despotović Vesna, Lazarević Marina, Uzelac Maria, Abramović Biljana, Vlazan Paulina, Ianăși Cătălin, Alapi Tünde, Náfrádi Máté, Maksimović Ivana, Putnik-Delić Marina, Šojić Merkulov Daniela

机构信息

Department of Chemistry, Biochemistry and Environmental Protection, University of Novi Sad Faculty of Sciences, Trg Dositeja Obradovića 3, 21000 Novi Sad, Serbia.

National Institute of Research and Development for Electrochemistry and Condensed Matter, Dr. Aurel Păunescu Podeanu 144, 300569 Timişoara, Romania.

出版信息

Nanomaterials (Basel). 2021 Jan 15;11(1):215. doi: 10.3390/nano11010215.

DOI:10.3390/nano11010215
PMID:33467696
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7829760/
Abstract

Pharmaceuticals and pesticides are emerging contaminants problematic in the aquatic environment because of their adverse effects on aquatic life and humans. In order to remove them from water, photocatalysis is one of the most modern technologies to be used. First, newly synthesized photocatalysts were successfully prepared using a sol-gel method and characterized by different techniques (XRD, FTIR, UV/Vis, BET and SEM/EDX). The photocatalytic properties of TiO, ZnO and MgO nanoparticles were examined according to their removal from water for two antibiotics (ciprofloxacin and ceftriaxone) and two herbicides (tembotrione and fluroxypyr) exposed to UV/simulated sunlight (SS). TiO proved to be the most efficient nanopowder under UV and SS. Addition of (NH)SO led to the faster removal of both antibiotics and herbicide fluroxypyr. The main intermediates were separated and identified for the herbicides and antibiotic ciprofloxacin. Finally, the toxicity of each emerging pollutant mixture and formed intermediates was assessed on wheat germination and biomass production.

摘要

药物和农药是水环境中出现的有问题的污染物，因为它们对水生生物和人类有不利影响。为了从水中去除它们，光催化是最常用的现代技术之一。首先，采用溶胶-凝胶法成功制备了新合成的光催化剂，并通过不同技术（XRD、FTIR、UV/Vis、BET和SEM/EDX）对其进行了表征。根据TiO、ZnO和MgO纳米颗粒对两种抗生素（环丙沙星和头孢曲松）和两种除草剂（苯唑草酮和氟草烟）在紫外线/模拟阳光（SS）照射下从水中的去除情况，考察了它们的光催化性能。TiO被证明是在紫外线和模拟阳光下最有效的纳米粉末。添加(NH)SO导致两种抗生素和除草剂氟草烟的去除速度更快。分离并鉴定了除草剂和抗生素环丙沙星的主要中间体。最后，评估了每种新兴污染物混合物及其形成的中间体对小麦发芽和生物量生产的毒性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/78016fa654b6/nanomaterials-11-00215-g018.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/d0c42d8780ae/nanomaterials-11-00215-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/066e34337ed7/nanomaterials-11-00215-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/a6a8fe4648f2/nanomaterials-11-00215-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/66ce2aff68f1/nanomaterials-11-00215-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/1f1fd6687fe9/nanomaterials-11-00215-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/c73a6aaa6f12/nanomaterials-11-00215-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/1e6df5b4657c/nanomaterials-11-00215-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/b30ca8d4cd72/nanomaterials-11-00215-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/f61036fb791f/nanomaterials-11-00215-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/cc01e84a791f/nanomaterials-11-00215-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/93344640e9d5/nanomaterials-11-00215-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/611415bf88fa/nanomaterials-11-00215-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/69340fb4a9ba/nanomaterials-11-00215-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/47b710c266b8/nanomaterials-11-00215-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/3e5275322870/nanomaterials-11-00215-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/0a6916ef0811/nanomaterials-11-00215-g016.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/265e2baf436d/nanomaterials-11-00215-g017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/78016fa654b6/nanomaterials-11-00215-g018.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/d0c42d8780ae/nanomaterials-11-00215-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/066e34337ed7/nanomaterials-11-00215-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/a6a8fe4648f2/nanomaterials-11-00215-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/66ce2aff68f1/nanomaterials-11-00215-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/1f1fd6687fe9/nanomaterials-11-00215-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/c73a6aaa6f12/nanomaterials-11-00215-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/1e6df5b4657c/nanomaterials-11-00215-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/b30ca8d4cd72/nanomaterials-11-00215-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/f61036fb791f/nanomaterials-11-00215-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/cc01e84a791f/nanomaterials-11-00215-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/93344640e9d5/nanomaterials-11-00215-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/611415bf88fa/nanomaterials-11-00215-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/69340fb4a9ba/nanomaterials-11-00215-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/47b710c266b8/nanomaterials-11-00215-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/3e5275322870/nanomaterials-11-00215-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/0a6916ef0811/nanomaterials-11-00215-g016.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/265e2baf436d/nanomaterials-11-00215-g017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/290a/7829760/78016fa654b6/nanomaterials-11-00215-g018.jpg

相似文献

1
Removal of Emerging Pollutants from Water Using Environmentally Friendly Processes: Photocatalysts Preparation, Characterization, Intermediates Identification and Toxicity Assessment.使用环境友好型工艺去除水中新兴污染物：光催化剂的制备、表征、中间体鉴定及毒性评估。
Nanomaterials (Basel). 2021 Jan 15;11(1):215. doi: 10.3390/nano11010215.
2
Banana Peel Extract-Derived ZnO Nanopowder: Transforming Solar Water Purification for Safer Agri-Food Production.香蕉皮提取物衍生的氧化锌纳米粉末：为更安全的农业食品生产变革太阳能水净化
Foods. 2024 Aug 22;13(16):2643. doi: 10.3390/foods13162643.
3
Photocatalytic removal of ceftriaxone from wastewater using TiO/MgO under ultraviolet radiation.利用 TiO/MgO 在紫外辐射下光催化去除废水中的头孢曲松。
Environ Res. 2023 Jul 15;229:115915. doi: 10.1016/j.envres.2023.115915. Epub 2023 Apr 17.
4
Photocatalytic degradation of phenol in water under simulated sunlight by an ultrathin MgO coated Ag/TiO nanocomposite.在模拟太阳光下，通过超薄 MgO 涂层的 Ag/TiO 纳米复合材料光催化降解水中的苯酚。
Chemosphere. 2019 Feb;216:1-8. doi: 10.1016/j.chemosphere.2018.10.083. Epub 2018 Oct 15.
5
UV/Vis Light Induced Degradation of Oxytetracycline Hydrochloride Mediated byCo-TiO Nanoparticles.载 Co-TiO2 纳米粒子的 UV/Vis 光诱导盐酸土霉素降解。
Molecules. 2020 Jan 7;25(2):249. doi: 10.3390/molecules25020249.
6
Low temperature preparation and visible light induced photocatalytic activity of europium doped hydrophobic anatase TiO2-SiO2 photocatalysts.铕掺杂疏水锐钛矿型TiO2-SiO2光催化剂的低温制备及可见光诱导光催化活性
J Nanosci Nanotechnol. 2010 Nov;10(11):7663-6. doi: 10.1166/jnn.2010.2776.
7
Ag-Coated Heterostructures of ZnO-TiO₂/Delaminated Montmorillonite as Solar Photocatalysts.ZnO-TiO₂/分层蒙脱石的银包覆异质结构作为太阳能光催化剂
Materials (Basel). 2017 Aug 17;10(8):960. doi: 10.3390/ma10080960.
8
Sunlight responsive WO₃/ZnO nanorods for photocatalytic degradation and mineralization of chlorinated phenoxyacetic acid herbicides in water.太阳光响应型 WO₃/ZnO 纳米棒用于水中光催化降解和矿化氯代苯氧乙酸类除草剂。
J Colloid Interface Sci. 2015 Jul 15;450:34-44. doi: 10.1016/j.jcis.2015.02.075. Epub 2015 Mar 10.
9
Sustainable Removal of Tolperisone from Waters by Application of Photocatalysis, Nanotechnology, and Chemometrics: Quantification, Environmental Toxicity, and Degradation Optimization.通过光催化、纳米技术和化学计量学实现水中托哌酮的可持续去除：定量、环境毒性及降解优化
Nanomaterials (Basel). 2022 Nov 25;12(23):4199. doi: 10.3390/nano12234199.
10
Enhanced Photocatalytic Degradation of the Imidazolinone Herbicide Imazapyr upon UV/Vis Irradiation in the Presence of CaMnO-TiO Hetero-Nanostructures: Degradation Pathways and Reaction Intermediates.在CaMnO-TiO异质纳米结构存在下，紫外/可见光照射增强咪唑啉酮类除草剂咪草烟的光催化降解：降解途径及反应中间体
Nanomaterials (Basel). 2020 May 8;10(5):896. doi: 10.3390/nano10050896.

引用本文的文献

1
Removal of organic micropollutants from water by adsorption on thermo-plasma expanded graphite encapsulated into calcium alginate.通过吸附在封装于海藻酸钙中的热等离子体膨胀石墨上从水中去除有机微污染物。
J Environ Health Sci Eng. 2023 Aug 23;21(2):497-512. doi: 10.1007/s40201-023-00876-9. eCollection 2023 Dec.
2
Sustainable Removal of Tolperisone from Waters by Application of Photocatalysis, Nanotechnology, and Chemometrics: Quantification, Environmental Toxicity, and Degradation Optimization.通过光催化、纳米技术和化学计量学实现水中托哌酮的可持续去除：定量、环境毒性及降解优化
Nanomaterials (Basel). 2022 Nov 25;12(23):4199. doi: 10.3390/nano12234199.
3

本文引用的文献

1
First report of pharmaceuticals and personal care products in two tropical rivers of southwestern India.首次在印度西南部的两条热带河流中检测到药品和个人护理产品。
Environ Monit Assess. 2020 Jul 17;192(8):529. doi: 10.1007/s10661-020-08480-2.
2
Ecotoxicological effects and accumulation of ciprofloxacin in Eichhornia crassipes under hydroponic conditions.水培条件下三氯生对水葫芦的生态毒理效应及积累。
Environ Sci Pollut Res Int. 2019 Oct;26(29):30348-30355. doi: 10.1007/s11356-019-06232-5. Epub 2019 Aug 21.
3
Effects of Ciprofloxacin and Roundup on seed germination and root development of maize.
Efficient Removal of Methylene Blue and Ciprofloxacin from Aqueous Solution Using Flower-like, Nanostructured ZnO Coating under UV Irradiation.
在紫外线照射下，利用花状纳米结构氧化锌涂层从水溶液中高效去除亚甲基蓝和环丙沙星。
Nanomaterials (Basel). 2022 Jun 26;12(13):2193. doi: 10.3390/nano12132193.
环丙沙星和农达对玉米种子萌发和根系发育的影响。
Sci Total Environ. 2019 Feb 15;651(Pt 2):2671-2678. doi: 10.1016/j.scitotenv.2018.09.365. Epub 2018 Oct 1.
4
Sunlight Assisted Photocatalytic Degradation of Ciprofloxacin in Water Using Fe Doped ZnO Nanoparticles for Potential Public Health Applications.阳光辅助铁掺杂 ZnO 纳米粒子光催化降解水中环丙沙星用于潜在的公共卫生应用。
Int J Environ Res Public Health. 2018 Nov 1;15(11):2440. doi: 10.3390/ijerph15112440.
5
Activation of persulfate by irradiated laterite for removal of fluoroquinolones in multi-component systems.辐照红土激活过硫酸盐去除多组分体系中的氟喹诺酮类药物。
J Hazard Mater. 2018 Mar 15;346:159-166. doi: 10.1016/j.jhazmat.2017.12.011. Epub 2017 Dec 6.
6
Small, mobile, persistent: Trifluoroacetate in the water cycle - Overlooked sources, pathways, and consequences for drinking water supply.小、移动、持久：水圈中的三氟乙酸——饮用水供应中被忽视的来源、途径和后果。
Water Res. 2017 Dec 1;126:460-471. doi: 10.1016/j.watres.2017.09.045. Epub 2017 Sep 26.
7
Exploring the Role of Persulfate in the Activation Process: Radical Precursor Versus Electron Acceptor.探索过硫酸盐在活化过程中的作用：自由基前体与电子受体。
Environ Sci Technol. 2017 Sep 5;51(17):10090-10099. doi: 10.1021/acs.est.7b02519. Epub 2017 Aug 16.
8
Antibiotics impact plant traits, even at small concentrations.抗生素会影响植物性状，即使浓度很低。
AoB Plants. 2017 Mar 13;9(2):plx010. doi: 10.1093/aobpla/plx010. eCollection 2017 Mar.
9
Fate and ecotoxicological impact of new generation herbicides from the triketone family: An overview to assess the environmental risks.三酮家族新一代除草剂的命运和生态毒理学影响：评估环境风险的概述。
J Hazard Mater. 2017 Mar 5;325:136-156. doi: 10.1016/j.jhazmat.2016.11.059. Epub 2016 Nov 21.
10
Adsorptive removal of ciprofloxacin by sodium alginate/graphene oxide composite beads from aqueous solution.海藻酸钠/氧化石墨烯复合微球对水溶液中 ciprofloxacin 的吸附去除
J Colloid Interface Sci. 2016 Dec 15;484:196-204. doi: 10.1016/j.jcis.2016.08.068. Epub 2016 Aug 29.