Impact of Titanium Dioxide in the Mechanical Recycling of Post-Consumer Polyethylene Terephthalate Bottle Waste: Tensile and Fracture Behavior.

This work provides an experimental analysis regarding the fracture behavior of recycled opaque PET (rPET-O) containing titanium dioxide (TiO) under plane stress conditions. For this purpose, a commercially post-consumer transparent colored/opaque PET flakes mix was processed using a semi-industrial extrusion calendering process. The manufactured rPET-O sheets had a TiO content of 1.45 wt.%. The mechanical and fracture properties of unaged and physically aged (1 year) samples were determined through uniaxial tensile experiments and the Essential Work of Fracture (EWF) methodology, respectively, and were compared to those of recycled transparent PET (rPET-T). Under tensile loading, independently of the aging time, rPET-O samples exhibited similar mechanical behavior as rPET-T up to the yield point. The main differences remained in the post-yielding region. The presence of TiO particles allowed reducing the strain energy density up to neck formation in aged samples. Regarding the EWF analysis, it is argued that the energy consumed up to the onset of crack propagation (w) for rPET-T was mainly dependent of the molecular mobility. That is, the w value decreased by 26% when rPET-T was physically aged. Interestingly, w values remained independent of the aging time for rPET-O. In fact, it was highlighted that before crack propagation, the EWF response was principally governed by matrix cavitation ahead of the crack tip, which allowed a significant release of the triaxial stress state independently of the molecular mobility. This property enabled rPET-O to exhibit a resistance to crack initiation 17% higher as compared to rPET-T when the material was physically aged. Finally, independently of the aging time, rPET-O exhibited a resistance to crack growth approximately 21% larger than rPET-T due to matrix fibrillation in large scale deformation.