Lucchesi Christophe, Vaillon Rodolphe, Chapuis Pierre-Olivier
Univ Lyon, CNRS, INSA-Lyon, Université Claude Bernard Lyon 1, CETHIL UMR5008, F-69621 Villeurbanne, France.
Nanoscale Horiz. 2021 Mar 1;6(3):201-208. doi: 10.1039/d0nh00609b. Epub 2021 Feb 3.
Energy transport theories are being revisited at the nanoscale, as macroscopic laws known for a century are broken at dimensions smaller than those associated with energy carriers. For thermal radiation, where the typical dimension is provided by Wien's wavelength, Planck's law and associated concepts describing surface-to-surface radiative transfer have to be replaced by a full electromagnetic framework capturing near-field radiative heat transfer (photon tunnelling between close bodies), interference effects and sub-wavelength thermal emission (emitting body of small size). It is only during the last decade that nanotechnology has allowed for many experimental verifications - with a recent boom - of the large increase of radiative heat transfer at the nanoscale. In this minireview, we highlight the parameter space that has been investigated until now, showing that it is limited in terms of inter-body distance, temperature and object size, and provide clues about possible thermal-energy harvesting, sensing and management applications. We also provide an outlook on open topics, underlining some difficulties in applying single-wavelength approaches to broadband thermal emitters while acknowledging the promise of thermal nanophotonics and observing that molecular/chemical viewpoints have been hardly addressed.
在纳米尺度下,能量传输理论正被重新审视,因为一个世纪以来为人熟知的宏观定律在小于与能量载体相关的尺寸时会失效。对于热辐射而言,其典型尺寸由维恩波长给出,描述表面到表面辐射传递的普朗克定律及相关概念必须被一个完整的电磁框架所取代,该框架涵盖近场辐射热传递(近距离物体之间的光子隧穿)、干涉效应和亚波长热发射(小尺寸发射体)。直到过去十年,纳米技术才使得许多关于纳米尺度下辐射热传递大幅增加的实验验证得以实现——且近期呈迅速发展态势。在本微型综述中,我们突出了迄今已被研究的参数空间,表明其在物体间距离、温度和物体尺寸方面存在局限,并提供了有关可能的热能收集、传感和管理应用的线索。我们还对开放课题进行了展望,强调了将单波长方法应用于宽带热发射体时存在的一些困难,同时认可热纳米光子学的前景,并指出分子/化学观点几乎未得到探讨。