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用于低温应用的大面积近场热光伏技术。

Large Area Near-Field Thermophotovoltaics for Low Temperature Applications.

作者信息

Selvidge Jennifer, France Ryan M, Goldsmith John, Solanki Parth, Steiner Myles A, Tervo Eric J

机构信息

National Renewable Energy Laboratory, Golden, CO, 80401, USA.

Department of Electrical & Computer Engineering, University of Wisconsin-Madison, Madison, WI, 53706, USA.

出版信息

Adv Mater. 2025 Feb;37(5):e2411524. doi: 10.1002/adma.202411524. Epub 2024 Dec 15.

Abstract

Thermophotovoltaics, devices that convert thermal infrared photons to electricity, offer a key pathway for a variety of critical renewable energy technologies including thermal energy storage, waste heat recovery, and direct solar-thermal power generation. However, conventional far-field devices struggle to generate reasonable powers at lower temperatures. Near-field thermophotovoltaics provide a pathway to substantially higher powers by leveraging photon tunneling effects. Here a large area near-field thermophotovoltaic device is presented, created with an epitaxial co-fabrication approach, that consists of a self-supported 0.28 cm emitter-cell pair with a 150 nm gap. The device generates 1.22 mW at 460 °C, a 25-fold increase over the same cell measured in a far-field configuration. Furthermore, the near-field device demonstrates short circuit current densities greater than the far-field photocurrent limit at all the temperatures tested, confirming the role of photon tunneling effects in the performance enhancement. Modeling suggests several practical directions for cell improvements and further increases in power density. These results highlight the promise of near-field thermophotovoltaics, especially for low temperature applications.

摘要

热光伏器件能够将热红外光子转化为电能,为包括热能存储、废热回收和直接太阳能-热能发电在内的多种关键可再生能源技术提供了一条关键途径。然而,传统的远场器件在较低温度下难以产生可观的功率。近场热光伏通过利用光子隧穿效应,为大幅提高功率提供了一条途径。本文展示了一种大面积近场热光伏器件,它采用外延共制造方法制成,由一个自支撑的0.28平方厘米发射极-电池对组成,间隙为150纳米。该器件在460°C时产生1.22毫瓦的功率,比在远场配置下测量的同一电池高出25倍。此外,近场器件在所有测试温度下的短路电流密度都大于远场光电流极限,证实了光子隧穿效应在性能增强中的作用。建模为电池改进和进一步提高功率密度提出了几个实际方向。这些结果凸显了近场热光伏的前景,特别是在低温应用方面。

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