Faculty of Chemistry, University of Bucharest, 050663 Bucharest, Romania.
Int J Mol Sci. 2021 Feb 3;22(4):1545. doi: 10.3390/ijms22041545.
Since the discovery in 1922 of 2,2-diphenyl-1-(2,4,6-trinitrophenyl) hydrazyl stable free radical (DPPH), the chemistry of such open-shell compounds has developed continuously, allowing for both theoretical and practical advances in the free radical chemistry area. This review presents the important, general and modern aspects of the chemistry of hydrazyl free radicals and the science behind it.
自 1922 年发现 2,2-二苯基-1-(2,4,6-三硝基苯基)腙稳定自由基(DPPH)以来,此类开壳化合物的化学不断发展,为自由基化学领域的理论和实际进展提供了可能。本综述介绍了腙自由基化学及其背后科学的重要、普遍和现代方面。