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用于食品应用的不同再生聚丙烯中挥发性和异味化合物的概况的重要性。

Importance of profile of volatile and off-odors compounds from different recycled polypropylene used for food applications.

作者信息

Paiva Robert, Wrona Magdalena, Nerín Cristina, Bertochi Veroneze Isabelly, Gavril Georgiana-Luminita, Andrea Cruz Sandra

机构信息

Chemistry Department, Center for Exact Sciences, Federal University of São Carlos (UFSCar), Rodovia Washington Luís, Km 235, 10 SP-310, São Carlos, Brazil.

Department of Analytical Chemistry, Aragon Institute of Engineering Research I3A, CPS-University of Zaragoza, Torres Quevedo Building, María de Luna 3, 50018 Zaragoza, Spain.

出版信息

Food Chem. 2021 Jul 15;350:129250. doi: 10.1016/j.foodchem.2021.129250. Epub 2021 Feb 9.

Abstract

Nowadays, polypropylene is one of the most common polymers used in the food packaging industry due to its good functionality and relatively low cost. Nevertheless, usage of plastic disposable packaging can be a generator of plastic pollution having negative environmental effects. A feasible solution for this issue would be to recycle. The polypropylene samples were submitted to two processes, forced contamination, and recycling, and they were analyzed by solid-phase microextraction gas chromatograph-olfactometry-mass spectrometry. 45 different volatile compounds were identified and 9 of them presented distinct odoriferous activities. Among them, two important markers were detected: diethyl phthalate (probably coming from the catalyst of PP polymerization, intentionally added substance (IAS)), and glycerine (a marker of non-intentionally added substances (NIAS)).

摘要

如今,聚丙烯因其良好的功能特性和相对较低的成本,成为食品包装行业中最常用的聚合物之一。然而,一次性塑料包装的使用可能会产生具有负面环境影响的塑料污染。解决这个问题的一个可行办法是回收利用。对聚丙烯样品进行了两种处理,强制污染和回收利用,并通过固相微萃取气相色谱 - 嗅觉测定 - 质谱联用仪进行分析。鉴定出45种不同的挥发性化合物,其中9种具有明显的气味活性。其中,检测到两个重要标志物:邻苯二甲酸二乙酯(可能来自聚丙烯聚合的催化剂、有意添加物质(IAS))和甘油(非有意添加物质(NIAS)的标志物)。

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