A Simple Turn-off Schiff Base Fluorescent Sensor for Copper (II) Ion and Its Application in Water Analysis.

An aniline-functionalized naphthalene dialdehyde Schiff base fluorescent probe with aggregation-induced enhanced emission (AIEE) characteristics was synthesized via a simple one-step condensation reaction and exhibited excellent sensitivity and selectivity towards copper(II) ions in aqueous media with a fluorescence " turn-off " phenomenon. The detection limit of the probe is 1.64 × 10 mol·L. Furthermore, according to the results of the UV-vis/fluorescence titrations, Job's plot method and H-NMR titrations, a 1:2 stoichiometry was identified. The binding constant between and Cu was calculated to be = 1.222 × 10. In addition, the AIEE fluorescent probe could be applied to detection in real water samples with satisfactory recoveries in the range 99.10-102.90% in lake water and 98.49-102.37% in tap water.