Suppr超能文献

用于光电化学水分解和CO还原的卤化物钙钛矿:挑战与机遇

Halide Perovskites for Photoelectrochemical Water Splitting and CO Reduction: Challenges and Opportunities.

作者信息

Bienkowski Krzysztof, Solarska Renata, Trinh Linh, Widera-Kalinowska Justyna, Al-Anesi Basheer, Liu Maning, Grandhi G Krishnamurthy, Vivo Paola, Oral Burcu, Yılmaz Beyza, Yıldırım Ramazan

机构信息

Centre of New Technologies, University of Warsaw, P.O. Box Banacha 2c, 02-097 Warsaw, Poland.

Department of Chemistry, Adelphi University, 1 South Avenue, Garden City, New York 11530, United States.

出版信息

ACS Catal. 2024 Apr 16;14(9):6603-6622. doi: 10.1021/acscatal.3c06040. eCollection 2024 May 3.

Abstract

Photoelectrochemical water splitting and CO reduction provide an attractive route to produce solar fuels while reducing the level of CO emissions. Metal halide perovskites (MHPs) have been extensively studied for this purpose in recent years due to their suitable optoelectronic properties. In this review, we survey the recent achievements in the field. After a brief introduction to photoelectrochemical (PEC) processes, we discussed the properties, synthesis, and application of MHPs in this context. We also survey the state-of-the-art findings regarding significant achievements in performance, and developments in addressing the major challenges of toxicity and instability toward water. Efforts have been made to replace the toxic Pb with less toxic materials like Sn, Ge, Sb, and Bi. The stability toward water has been also improved by using various methods such as compositional engineering, 2D/3D perovskite structures, surface passivation, the use of protective layers, and encapsulation. In the last part, considering the experience gained in photovoltaic applications, we provided our perspective for the future challenges and opportunities. We place special emphasis on the improvement of stability as the major challenge and the potential contribution of machine learning to identify the most suitable formulation for halide perovskites with desired properties.

摘要

光电化学水分解和CO还原为生产太阳能燃料提供了一条有吸引力的途径,同时降低了CO排放水平。近年来,金属卤化物钙钛矿(MHPs)因其合适的光电特性而被广泛研究用于此目的。在本综述中,我们概述了该领域的最新成就。在简要介绍光电化学(PEC)过程之后,我们在此背景下讨论了MHPs的性质、合成及应用。我们还综述了关于性能方面重大成就以及在解决对水的毒性和不稳定性等主要挑战方面的进展的最新研究结果。人们已努力用Sn、Ge、Sb和Bi等毒性较小的材料替代有毒的Pb。通过诸如成分工程、二维/三维钙钛矿结构、表面钝化、使用保护层和封装等各种方法,对水的稳定性也得到了提高。在最后一部分,考虑到在光伏应用中获得的经验,我们阐述了对未来挑战和机遇的看法。我们特别强调将提高稳定性作为主要挑战,以及机器学习在识别具有所需特性的卤化物钙钛矿最合适配方方面的潜在贡献。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f7bc/11075028/b57a976f93e3/cs3c06040_0001.jpg

相似文献

1
Halide Perovskites for Photoelectrochemical Water Splitting and CO Reduction: Challenges and Opportunities.
ACS Catal. 2024 Apr 16;14(9):6603-6622. doi: 10.1021/acscatal.3c06040. eCollection 2024 May 3.
2
Photoelectrochemical Water Splitting Reaction System Based on Metal-Organic Halide Perovskites.
Materials (Basel). 2020 Jan 3;13(1):210. doi: 10.3390/ma13010210.
3
Emerging doping strategies in two-dimensional hybrid perovskite semiconductors for cutting edge optoelectronics applications.
Nanoscale Adv. 2022 Jan 19;4(4):995-1025. doi: 10.1039/d1na00709b. eCollection 2022 Feb 15.
4
"Unleaded" Perovskites: Status Quo and Future Prospects of Tin-Based Perovskite Solar Cells.
Adv Mater. 2019 Nov;31(47):e1803230. doi: 10.1002/adma.201803230. Epub 2018 Oct 1.
5
Bismuth-Based Halide Perovskites for Photocatalytic H Evolution Application.
Molecules. 2023 Jan 1;28(1):339. doi: 10.3390/molecules28010339.
6
Bismuth Halide Perovskite-Like Materials: Current Opportunities and Challenges.
ChemSusChem. 2019 Apr 23;12(8):1612-1630. doi: 10.1002/cssc.201802930. Epub 2019 Mar 19.
7
Highly Stable Inorganic Lead Halide Perovskite toward Efficient Photovoltaics.
Acc Chem Res. 2021 Sep 7;54(17):3452-3461. doi: 10.1021/acs.accounts.1c00343. Epub 2021 Aug 24.
8
Single Crystal Sn-Based Halide Perovskites.
Nanomaterials (Basel). 2024 Sep 4;14(17):1444. doi: 10.3390/nano14171444.
9
Organometal Halide Perovskite-Based Photoelectrochemical Module Systems for Scalable Unassisted Solar Water Splitting.
Adv Sci (Weinh). 2023 Nov;10(33):e2303106. doi: 10.1002/advs.202303106. Epub 2023 Sep 26.
10
Metal-Halide Perovskite Transistors for Printed Electronics: Challenges and Opportunities.
Adv Mater. 2017 Dec;29(46). doi: 10.1002/adma.201702838. Epub 2017 Oct 12.

引用本文的文献

2
Halide Perovskite Photocatalysts for Clean Fuel Production and Organic Synthesis: Opportunities and Challenges.
Adv Mater. 2025 Jul;37(28):e2419603. doi: 10.1002/adma.202419603. Epub 2025 May 9.
3
Chemistry of Materials Underpinning Photoelectrochemical Solar Fuel Production.
Chem Rev. 2025 May 28;125(10):4768-4839. doi: 10.1021/acs.chemrev.4c00258. Epub 2025 May 6.
4
Synergistic metal halide perovskite@metal-organic framework hybrids for photocatalytic CO reduction.
iScience. 2024 Sep 11;27(10):110924. doi: 10.1016/j.isci.2024.110924. eCollection 2024 Oct 18.

本文引用的文献

1
All-inorganic lead halide perovskites for photocatalysis: a review.
RSC Adv. 2024 Feb 7;14(7):4946-4965. doi: 10.1039/d3ra07998h. eCollection 2024 Jan 31.
2
CuZnSnS (CZTS) for Photoelectrochemical CO Reduction: Efficiency, Selectivity, and Stability.
Nanomaterials (Basel). 2023 Oct 15;13(20):2762. doi: 10.3390/nano13202762.
3
Organometal Halide Perovskite-Based Photoelectrochemical Module Systems for Scalable Unassisted Solar Water Splitting.
Adv Sci (Weinh). 2023 Nov;10(33):e2303106. doi: 10.1002/advs.202303106. Epub 2023 Sep 26.
6
Metal-free reduction of CO to formate using a photochemical organohydride-catalyst recycling strategy.
Nat Chem. 2023 Jun;15(6):794-802. doi: 10.1038/s41557-023-01157-6. Epub 2023 Mar 23.
7
Dimensionality engineering of metal halide perovskites.
Front Optoelectron. 2020 Sep;13(3):196-224. doi: 10.1007/s12200-020-1039-6. Epub 2020 Aug 6.
8
Floating perovskite-BiVO devices for scalable solar fuel production.
Nature. 2022 Aug;608(7923):518-522. doi: 10.1038/s41586-022-04978-6. Epub 2022 Aug 17.
9
Stabilization and Performance Enhancement Strategies for Halide Perovskite Photocatalysts.
Adv Mater. 2023 Feb;35(6):e2203836. doi: 10.1002/adma.202203836. Epub 2022 Dec 27.
10
Long-term solar water and CO splitting with photoelectrochemical BiOI-BiVO tandems.
Nat Mater. 2022 Aug;21(8):864-868. doi: 10.1038/s41563-022-01262-w. Epub 2022 May 26.

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型,支持多种主流文档格式。

立即体验