线性有机聚合物负载铱配合物作为可循环利用的自动串联催化剂，用于通过从α-氨基苯甲腈选择性水合/无受体脱氢偶联合成喹唑啉酮。
Linear-Organic-Polymer-Supported Iridium Complex as a Recyclable Auto-Tandem Catalyst for the Synthesis of Quinazolinones via Selective Hydration/Acceptorless Dehydrogenative Coupling from -Aminobenzonitriles.
作者信息
Hao Shushu, Yang Jiazhi, Liu Peng, Xu Jing, Yang Chenchen, Li Feng
机构信息
School of Chemical Engineering, Nanjing University of Science & Technology, Nanjing 210094, P. R. China.
出版信息
Org Lett. 2021 Apr 2;23(7):2553-2558. doi: 10.1021/acs.orglett.1c00475. Epub 2021 Mar 17.
A linear-organic-polymer-supported iridium complex CpIr@P4VP, which is designed and synthesized by the coordinative immobilization of [CpIrCl] on poly(4-vinylpyridine), was proven to be an efficient heterogeneous autotandem catalyst for synthesizing quinazolinones via selective hydration/acceptorless dehydrogenative coupling from -aminobenzonitriles. Furthermore, the synthesized catalyst was recycled five times without an obvious decrease in the catalytic activity.
一种线性有机聚合物负载的铱配合物CpIr@P4VP，它是通过[CpIrCl]与聚（4-乙烯基吡啶）的配位固定化设计合成的，被证明是一种高效的多相自串联催化剂，可通过从氨基苯腈选择性水合/无受体脱氢偶联合成喹唑啉酮。此外，合成的催化剂循环使用了五次，催化活性没有明显下降。
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