Schopf Roland, Schmidt Florian, Linner Johanna, Kulozik Ulrich
Chair of Food and Bioprocess Engineering, TUM School of Life Sciences, Technical University of Munich, Weihenstephaner Berg 1, 85354 Freising, Germany.
Foods. 2021 Mar 24;10(4):692. doi: 10.3390/foods10040692.
The fractionation efficiency of hollow fiber membranes (HFM) for milk protein fractionation was compared to ceramic tubular membranes (CTM) and spiral wound membranes (SWM). HFM combine the features of high membrane packing density of SWM and the more defined flow conditions and better control of membrane fouling in the open flow channel cross-sections of CTM. The aim was to comparatively analyze the effect of variations in local pressure and flow conditions while using single industrially sized standard modules with similar dimensions and module footprints (module diameter and length). The comparative assessment with varied transmembrane pressure was first applied for a constant feed volume flow rate of 20 m h and, secondly, with the same axial pressure drop along the modules of 1.3 bar m, similar to commonly applied crossflow velocity and wall shear stress conditions at the industrial level. Flux, transmission factor of proteins (whey proteins and serum caseins), and specific protein mass flow per area membrane and per volume of module installed were determined as the evaluation criteria. The casein-to-whey protein ratios were calculated as a measure for protein fractionation effect. Results obtained show that HFM, which so far are under-represented as standard module types in industrial dairy applications, appear to be a competitive alternative to SWM and CTM for milk protein fractionation.
将中空纤维膜(HFM)用于乳蛋白分离的分离效率与陶瓷管式膜(CTM)和螺旋卷式膜(SWM)进行了比较。中空纤维膜兼具螺旋卷式膜的高膜装填密度以及陶瓷管式膜在开放流道横截面中更明确的流动条件和对膜污染更好控制的特点。目的是在使用尺寸和模块占地面积(模块直径和长度)相似的单个工业规模标准模块时,比较分析局部压力和流动条件变化的影响。首先,在恒定进料体积流量为20 m³/h的情况下,对不同的跨膜压力进行比较评估;其次,在沿模块的轴向压降相同为1.3 bar/m的情况下进行评估,这类似于工业水平上常用的错流速度和壁面剪应力条件。通量、蛋白质(乳清蛋白和血清酪蛋白)的透过系数以及每单位膜面积和每单位已安装模块体积的特定蛋白质质量流量被确定为评估标准。计算酪蛋白与乳清蛋白的比率作为蛋白质分离效果的衡量指标。所得结果表明,中空纤维膜在工业乳制品应用中作为标准模块类型目前代表性不足,但对于乳蛋白分离而言,似乎是螺旋卷式膜和陶瓷管式膜的一种有竞争力的替代方案。