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硫钒铜矿:纳米尺度下的前景

Sulvanites: The Promise at the Nanoscale.

作者信息

Prado-Rivera Roberto, Chang Chen-Yu, Liu Mimi, Lai Cheng-Yu, Radu Daniela R

机构信息

Department of Mechanical and Materials Engineering, Florida International University, Miami, FL 33199, USA.

出版信息

Nanomaterials (Basel). 2021 Mar 23;11(3):823. doi: 10.3390/nano11030823.

DOI:10.3390/nano11030823
PMID:33807005
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8005093/
Abstract

The class of ternary copper chalcogenides CuMX (M = V, Nb, Ta; X = S, Se, Te), also known as the sulvanite family, has attracted attention in the past decade as featuring promising materials for optoelectronic devices, including solar photovoltaics. Experimental and theoretical studies of these semiconductors have provided much insight into their properties, both in bulk and at the nanoscale. The recent realization of sulvanites at the nanoscale opens new avenues for the compounds toward printable electronics. This review is aimed at the consideration of synthesis methods, relevant properties and the recent developments of the most important sulvanites.

摘要

三元铜硫属化合物CuMX(M = V、Nb、Ta;X = S、Se、Te),也被称为硫钒铜矿族,在过去十年中受到了关注,因为它们是包括太阳能光伏在内的光电器件的有前景的材料。对这些半导体的实验和理论研究为其在体相和纳米尺度下的性质提供了很多见解。最近在纳米尺度实现硫钒铜矿为这些化合物通向可印刷电子学开辟了新途径。本综述旨在探讨最重要的硫钒铜矿的合成方法、相关性质及最新进展。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/138f/8005093/bc2843eebab2/nanomaterials-11-00823-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/138f/8005093/e1f85c38c824/nanomaterials-11-00823-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/138f/8005093/4f47f1447e20/nanomaterials-11-00823-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/138f/8005093/f2c1a325cc8e/nanomaterials-11-00823-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/138f/8005093/9daa42bbd4cf/nanomaterials-11-00823-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/138f/8005093/4e98bbf30447/nanomaterials-11-00823-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/138f/8005093/c56a9d1d52c2/nanomaterials-11-00823-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/138f/8005093/bc2843eebab2/nanomaterials-11-00823-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/138f/8005093/e1f85c38c824/nanomaterials-11-00823-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/138f/8005093/4f47f1447e20/nanomaterials-11-00823-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/138f/8005093/f2c1a325cc8e/nanomaterials-11-00823-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/138f/8005093/9daa42bbd4cf/nanomaterials-11-00823-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/138f/8005093/4e98bbf30447/nanomaterials-11-00823-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/138f/8005093/c56a9d1d52c2/nanomaterials-11-00823-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/138f/8005093/bc2843eebab2/nanomaterials-11-00823-g007.jpg

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本文引用的文献

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Sci Rep. 2020 Dec 10;10(1):21679. doi: 10.1038/s41598-020-78649-9.
2
Synthesis and optoelectronic properties of Cu3VSe4 nanocrystals.Cu3VSe4 纳米晶体的合成及光电性能。
PLoS One. 2020 May 5;15(5):e0232184. doi: 10.1371/journal.pone.0232184. eCollection 2020.
3
Cu MS (M=V, Nb, Ta) and its Solid Solutions with Sulvanite Structure for Photocatalytic and Photoelectrochemical H Evolution under Visible-Light Irradiation.
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ACS Omega. 2022 May 31;7(23):19070-19079. doi: 10.1021/acsomega.1c06795. eCollection 2022 Jun 14.
具有硫钒铜矿结构的铜 MS(M = V、Nb、Ta)及其固溶体在可见光照射下用于光催化和光电化学析氢
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