固态光化学诱导动态核极化

Photo-CIDNP in Solid State.

作者信息

Matysik Jörg, Ding Yonghong, Kim Yunmi, Kurle Patrick, Yurkovskaya Alexandra, Ivanov Konstantin, Alia A

机构信息

Institut für Analytische Chemie, Universität Leipzig, Linnéstr. 3, 04103 Leipzig, Germany.

International Tomography Center, Institutskaya, 630090 Novosibirsk, Russia.

出版信息

Appl Magn Reson. 2022;53(3-5):521-537. doi: 10.1007/s00723-021-01322-5. Epub 2021 Apr 6.

Photo-CIDNP (photo-chemically induced dynamic nuclear polarization) refers to nuclear polarization created by the spin-chemical evolution of spin-correlated radical pairs (SCRPs). This phenomenon occurs in gases, liquids and solids. Based on the solid-state photo-CIDNP effect observed under magic-angle spinning (MAS), photo-CIDNP MAS NMR has been developed as analytical method. Here we report the origin, the theory and the state of the art of this method.