Manna Rakesh, Srivastava Suneel Kumar
Department of Chemistry, Indian Institute of Technology Kharagpur, Kharagpur 721302, West Bengal, India.
ACS Omega. 2021 Mar 22;6(13):9164-9175. doi: 10.1021/acsomega.1c00382. eCollection 2021 Apr 6.
The present work is focused on fabrication of reduced graphene oxide/iron(II/III) oxide/polyaniline (RGO/FeO/PANI) ternary composite by a hydrothermal method, its characterization, and application in the development of a high microwave absorbing shielding material. The RGO/FeO/PANI composite showed dramatic enhancement of dielectric loss and magnetic loss compared to FeO/PANI and RGO/FeO binary composites. This is ascribed to the embedment of more heterostructure phases. As a result, RGO/FeO/PANI showed remarkably high SE (∼28 dB) through the absorption dominant mechanism. Our findings also showed maximum of FeO/PANI, RGO/FeO, and RGO/FeO/PANI in the range of 2-8 GHz corresponding to -25 to -35, -40 to -46, and approximately -64 dB, respectively. This is in all probability due to the good impedance matching between permittivity/permeability and dielectric/magnetic losses.
本工作聚焦于通过水热法制备还原氧化石墨烯/铁(II/III)氧化物/聚苯胺(RGO/FeO/PANI)三元复合材料,对其进行表征,并将其应用于开发一种高微波吸收屏蔽材料。与FeO/PANI和RGO/FeO二元复合材料相比,RGO/FeO/PANI复合材料表现出显著增强的介电损耗和磁损耗。这归因于更多异质结构相的嵌入。结果,RGO/FeO/PANI通过吸收主导机制表现出极高的屏蔽效能(SE)(约28 dB)。我们的研究结果还表明,FeO/PANI、RGO/FeO和RGO/FeO/PANI的最大值分别在2 - 8 GHz范围内,对应于-25至-35 dB、-40至-46 dB和约-64 dB。这很可能是由于介电常数/磁导率与介电/磁损耗之间良好的阻抗匹配。