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还原氧化石墨烯/氧化亚铁/聚苯胺三元复合材料作为电磁污染屏蔽中的优异微波吸收剂

Reduced Graphene Oxide/FeO/Polyaniline Ternary Composites as a Superior Microwave Absorber in the Shielding of Electromagnetic Pollution.

作者信息

Manna Rakesh, Srivastava Suneel Kumar

机构信息

Department of Chemistry, Indian Institute of Technology Kharagpur, Kharagpur 721302, West Bengal, India.

出版信息

ACS Omega. 2021 Mar 22;6(13):9164-9175. doi: 10.1021/acsomega.1c00382. eCollection 2021 Apr 6.

Abstract

The present work is focused on fabrication of reduced graphene oxide/iron(II/III) oxide/polyaniline (RGO/FeO/PANI) ternary composite by a hydrothermal method, its characterization, and application in the development of a high microwave absorbing shielding material. The RGO/FeO/PANI composite showed dramatic enhancement of dielectric loss and magnetic loss compared to FeO/PANI and RGO/FeO binary composites. This is ascribed to the embedment of more heterostructure phases. As a result, RGO/FeO/PANI showed remarkably high SE (∼28 dB) through the absorption dominant mechanism. Our findings also showed maximum of FeO/PANI, RGO/FeO, and RGO/FeO/PANI in the range of 2-8 GHz corresponding to -25 to -35, -40 to -46, and approximately -64 dB, respectively. This is in all probability due to the good impedance matching between permittivity/permeability and dielectric/magnetic losses.

摘要

本工作聚焦于通过水热法制备还原氧化石墨烯/铁(II/III)氧化物/聚苯胺(RGO/FeO/PANI)三元复合材料,对其进行表征,并将其应用于开发一种高微波吸收屏蔽材料。与FeO/PANI和RGO/FeO二元复合材料相比,RGO/FeO/PANI复合材料表现出显著增强的介电损耗和磁损耗。这归因于更多异质结构相的嵌入。结果,RGO/FeO/PANI通过吸收主导机制表现出极高的屏蔽效能(SE)(约28 dB)。我们的研究结果还表明,FeO/PANI、RGO/FeO和RGO/FeO/PANI的最大值分别在2 - 8 GHz范围内,对应于-25至-35 dB、-40至-46 dB和约-64 dB。这很可能是由于介电常数/磁导率与介电/磁损耗之间良好的阻抗匹配。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/59bd/8028133/fc6fd5004dbf/ao1c00382_0002.jpg

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