Shojaei Iraj Abbasian, Pournia Seyyedesadaf, Le Congcong, Ortiz Brenden R, Jnawali Giriraj, Zhang Fu-Chun, Wilson Stephen D, Jackson Howard E, Smith Leigh M
Department of Physics, University of Cincinnati, Cincinnati, OH, USA.
Kavli Institute of Theoretical Sciences, University of Chinese Academy of Sciences, Beijing, 100190, China.
Sci Rep. 2021 Apr 14;11(1):8155. doi: 10.1038/s41598-021-87302-y.
There is tremendous interest in measuring the strong electron-phonon interactions seen in topological Weyl semimetals. The semimetal NbIrTe has been proposed to be a Type-II Weyl semimetal with 8 pairs of opposite Chirality Weyl nodes which are very close to the Fermi energy. We show using polarized angular-resolved micro-Raman scattering at two excitation energies that we can extract the phonon mode dependence of the Raman tensor elements from the shape of the scattering efficiency versus angle. This van der Waals semimetal with broken inversion symmetry and 24 atoms per unit cell has 69 possible phonon modes of which we measure 19 modes with frequencies and symmetries consistent with Density Functional Theory calculations. We show that these tensor elements vary substantially in a small energy range which reflects a strong variation of the electron-phonon coupling for these modes.
人们对测量拓扑外尔半金属中强电子-声子相互作用有着极大的兴趣。半金属NbIrTe被认为是一种II型外尔半金属,具有8对相反手性的外尔节点,这些节点非常接近费米能级。我们通过在两个激发能量下使用偏振角分辨微拉曼散射表明,我们可以从散射效率与角度的关系形状中提取拉曼张量元素的声子模式依赖性。这种具有破缺空间反演对称性且每单位晶胞有24个原子的范德华半金属有69种可能的声子模式,我们测量了其中19种模式,其频率和对称性与密度泛函理论计算结果一致。我们表明,这些张量元素在一个小能量范围内有很大变化,这反映了这些模式的电子-声子耦合有很强的变化。