Li Zhuoyi, Ma Xu, Chen Danke, Wan Xinyi, Wang Xiaobin, Fang Zhou, Peng Xinsheng
State Key Laboratory of Silicon Materials School of Materials Science and Engineering ERC of Membrane and Water Treatment Zhejiang University Hangzhou 310027 P. R. China.
Adv Sci (Weinh). 2021 Feb 1;8(7):2004552. doi: 10.1002/advs.202004552. eCollection 2021 Apr.
Though evaporation-driven electricity generation has emerged as a novel eco-friendly energy and attracted intense interests, it is typically demonstrated in pure water or a very low salt concentration. Integrating evaporation-driven electricity generation and solar steam desalination simultaneously should be more promising. Herein, a polyaniline coated metal-organic frameworks (MOFs) nanorod arrays membrane is synthesized which inherits the merits of both polyaniline and MOFs, demonstrating nice stability, good interfacial solar steam desalination, and evaporation-driven electricity generation. Moreover, an integrated system based on this hybrid membrane achieves good interfacial solar-heating evaporation and prominently enhanced evaporation-driven electricity generation under one sun. Notably, the realization of effective seawater desalination and efficient evaporation-driven electricity generation simultaneously by the non-carbon-based materials is reported for the first time, which provides a new alternative way for cogenerating both freshwater and electricity by harvesting energy from seawater and solar light.
尽管蒸发驱动发电已成为一种新型的环保能源并引起了广泛关注,但它通常是在纯水或极低盐浓度的环境中得到展示。同时集成蒸发驱动发电和太阳能蒸汽淡化应该更具前景。在此,合成了一种聚苯胺包覆的金属有机框架(MOFs)纳米棒阵列膜,该膜兼具聚苯胺和MOFs的优点,表现出良好的稳定性、出色的界面太阳能蒸汽淡化性能以及蒸发驱动发电能力。此外,基于这种复合膜的集成系统在一个太阳光照强度下实现了良好的界面太阳能加热蒸发,并显著增强了蒸发驱动发电。值得注意的是,首次报道了通过非碳基材料同时实现有效的海水淡化和高效的蒸发驱动发电,这为从海水和太阳光中获取能量同时生产淡水和电力提供了一种新的替代方法。