A Silver-Loaded Exfoliated Graphite Nanocomposite Anti-Fouling Electrochemical Sensor for Bisphenol A in Thermal Paper Samples.

Silver nanoparticles (AgNPs) were synthesized separately and loaded onto the expanded layers of exfoliated graphite (EG) to form a silver nanoparticle-exfoliated graphite nanocomposite (AgNPs-EG). The AgNPs-EG was compressed into a pellet (0.6 cm in diameter) and used to prepare an electrochemical sensor for bisphenol A (BPA) in standard samples and in thermal paper. The synthesized materials were characterized by ultraviolet-visible spectrophotometry, X-ray diffraction spectroscopy, scanning electron microscopy, and energy-dispersive X-ray. The electrochemical behavior of BPA on the AgNPs-EG sensor was investigated by cyclic voltammetry and square wave voltammetry. Under optimized experimental conditions, the oxidation peak current was linearly proportional to bisphenol A concentrations in the range from 5.0 to100 μM, with a coefficient of determination ( ) of 0.9981. The obtained limit of detection of the method was 0.23 μM. The fabricated sensor was able to overcome electrode fouling with good reproducibility (RSD = 2.62%, = 5) by mechanical polishing of the electrode on emery paper. The proposed method was successfully applied to determine bisphenol A in thermal paper samples and demonstrated good accuracy of 93.1 to 113% recovery.