Al Rai Adel, Yanilmaz Meltem
Faculty of Aeronautics and Astronautics, Istanbul Technical University, Istanbul, 34469 Turkey.
Nano Science and Nano Engineering, Istanbul Technical University, Istanbul, 34469 Turkey.
Cellulose (Lond). 2021;28(9):5169-5218. doi: 10.1007/s10570-021-03881-z. Epub 2021 Apr 18.
Polyacrylonitrile (PAN)-based carbon precursor is a well-established and researched material for electrodes in energy storage applications due to its good physical properties and excellent electrochemical performance. However, in the fight of preserving the environment and pioneering renewable energy sources, environmentally sustainable carbon precursors with superior electrochemical performance are needed. Therefore, bio-based materials are excellent candidates to replace PAN as a carbon precursor. Depending on the design requirement (e.g. carbon morphology, doping level, specific surface area, pore size and volume, and electrochemical performance), the appropriate selection of carbon precursors can be made from a variety of biomass and biowaste materials. This review provides a summary and discussion on the preparation and characterization of the emerging and recent bio-based carbon precursors that can be used as electrodes in energy storage applications. The review is outlined based on the morphology of nanostructures and the precursor's type. Furthermore, the review discusses and summarizes the excellent electrochemical performance of these recent carbon precursors in storage energy applications. Finally, a summary and outlook are also given. All this together portrays the promising role of bio-based carbon electrodes in energy storage applications.
聚丙烯腈(PAN)基碳前驱体因其良好的物理性能和出色的电化学性能,是储能应用中电极材料方面一种成熟且经过深入研究的材料。然而,在保护环境和开拓可再生能源的进程中,需要具备卓越电化学性能的环境可持续型碳前驱体。因此,生物基材料是替代PAN作为碳前驱体的理想选择。根据设计要求(如碳形态、掺杂水平、比表面积、孔径和孔体积以及电化学性能),可以从各种生物质和生物废料中适当选择碳前驱体。本文综述总结并讨论了可用于储能应用电极的新型生物基碳前驱体的制备与表征。该综述基于纳米结构的形态和前驱体类型进行概述。此外,还讨论并总结了这些新型碳前驱体在储能应用中的优异电化学性能。最后,给出了总结与展望。所有这些共同描绘了生物基碳电极在储能应用中的广阔前景。