碘催化吲哚的硫烯丙基化反应，使用 Baylis-Hillman 溴化物制备的 Bunte 盐。
Iodine-catalyzed thioallylation of indoles using Bunte salts prepared from Baylis-Hillman bromides.
机构信息
Department of Chemistry, Institute of Science, Banaras Hindu University, Varanasi 221005, India.
出版信息
Org Biomol Chem. 2021 Apr 26;19(15):3484-3488. doi: 10.1039/d1ob00377a.
PMID:33899895
Abstract
Metal-free iodine-catalyzed regioselective thioallylation of indoles has been accomplished at room temperature using Bunte salts prepared from Baylis-Hillman bromides. The resulting multi-functional C3 thioallylated indoles exhibit ample structural diversity and good functional group tolerance.
摘要
室温条件下，使用由 Baylis-Hillman 溴化物制备的 Bunte 盐，实现了吲哚的无金属碘催化区域选择性硫烯丙基化反应。得到的多功能 C3 硫烯丙基化吲哚具有丰富的结构多样性和良好的官能团耐受性。
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