Ying Zhiwei, Huang Lu, Ji Lili, Li He, Liu Xinqi, Zhang Chi, Zhang Jian, Yi Guofu
National Soybean Processing Industry Technology Innovation Center, Beijing Technology and Business University (BTBU), Beijing 100048, China.
Beijing Advanced Innovation Center for Food Nutrition and Human Health, Beijing Engineering and Technology Research Center of Food Additives, Beijing Technology and Business University (BTBU), Beijing 100048, China.
Materials (Basel). 2021 Apr 2;14(7):1754. doi: 10.3390/ma14071754.
Porous carbon material with high specific surface area was prepared from soybean dreg by a simple and effective two-step method (high temperature pyrolysis and activation). The structural characteristics of the synthesized carbon were evaluated by Brunauer-Emmett-Teller (BET), N adsorption/desorption measurements/techniques, an elemental analyzer (EA), scanning electron microscopy equipped with energy dispersive X-ray spectroscopy (SEM-EDS), transmission electron microscopy (TEM), an X-ray diffractometer (XRD), Raman spectroscopy (Raman), a Fourier transform infrared spectrometer (FTIR), and X-ray photoelectron spectroscopy (XPS). The specific surface area of SDB-6-K was 2786 m g, the pore volume was 2.316 cm g, and the average pore size was 3.326 nm. The high specific surface area and effective functional groups of carbon material promoted the adsorption of methylene blue. The maximum adsorption capacity of SDB-6-K to methylene blue was 2636 mg g at 318 K. The adsorption kinetic and isotherm data were most suitable for pseudo-second-order and Langmuir equations. The results showed that the adsorbent had excellent adsorptive ability and had good practical application potential in the field of dye wastewater treatment in the future.
采用简单有效的两步法(高温热解和活化)由豆渣制备了具有高比表面积的多孔碳材料。通过布鲁诺尔-埃米特-泰勒(BET)、N2吸附/脱附测量/技术、元素分析仪(EA)、配备能量色散X射线光谱仪的扫描电子显微镜(SEM-EDS)、透射电子显微镜(TEM)、X射线衍射仪(XRD)、拉曼光谱(Raman)、傅里叶变换红外光谱仪(FTIR)和X射线光电子能谱(XPS)对合成碳的结构特征进行了评估。SDB-6-K的比表面积为2786 m2/g,孔容为2.316 cm3/g,平均孔径为3.326 nm。碳材料的高比表面积和有效的官能团促进了亚甲基蓝的吸附。SDB-6-K在318 K下对亚甲基蓝的最大吸附容量为2636 mg/g。吸附动力学和等温线数据最适合拟二级和朗缪尔方程。结果表明,该吸附剂具有优异的吸附能力,在未来染料废水处理领域具有良好的实际应用潜力。