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嵌入单层金纳米粒子的高性能非易失性铟镓锌氧化物基闪存器件

High-Performance Non-Volatile InGaZnO Based Flash Memory Device Embedded with a Monolayer Au Nanoparticles.

作者信息

Naqi Muhammad, Kwon Nayoung, Jung Sung Hyeon, Pujar Pavan, Cho Hae Won, Cho Yong In, Cho Hyung Koun, Lim Byungkwon, Kim Sunkook

机构信息

Department of Advanced Materials Science and Engineering, Sungkyunkwan University, Suwon 16419, Korea.

出版信息

Nanomaterials (Basel). 2021 Apr 24;11(5):1101. doi: 10.3390/nano11051101.

Abstract

Non-volatile memory (NVM) devices based on three-terminal thin-film transistors (TFTs) have gained extensive interest in memory applications due to their high retained characteristics, good scalability, and high charge storage capacity. Herein, we report a low-temperature (<100 °C) processed top-gate TFT-type NVM device using indium gallium zinc oxide (IGZO) semiconductor with monolayer gold nanoparticles (AuNPs) as a floating gate layer to obtain reliable memory operations. The proposed NVM device exhibits a high memory window (ΔV) of 13.7 V when it sweeps from -20 V to +20 V back and forth. Additionally, the material characteristics of the monolayer AuNPs (floating gate layer) and IGZO film (semiconductor layer) are confirmed using transmission electronic microscopy (TEM), atomic force microscopy (AFM), and x-ray photoelectron spectroscopy (XPS) techniques. The memory operations in terms of endurance and retention are obtained, revealing highly stable endurance properties of the device up to 100 P/E cycles by applying pulses (±20 V, duration of 100 ms) and reliable retention time up to 10 s. The proposed NVM device, owing to the properties of large memory window, stable endurance, and high retention time, enables an excellent approach in futuristic non-volatile memory technology.

摘要

基于三端薄膜晶体管(TFT)的非易失性存储器(NVM)器件因其高保持特性、良好的可扩展性和高电荷存储容量,在存储器应用中受到了广泛关注。在此,我们报道了一种低温(<100°C)处理的顶栅TFT型NVM器件,该器件使用氧化铟镓锌(IGZO)半导体,并以单层金纳米颗粒(AuNP)作为浮栅层,以实现可靠的存储操作。当该器件在-20V至+20V之间来回扫描时,所提出的NVM器件表现出13.7V的高存储窗口(ΔV)。此外,使用透射电子显微镜(TEM)、原子力显微镜(AFM)和X射线光电子能谱(XPS)技术确认了单层AuNP(浮栅层)和IGZO薄膜(半导体层)的材料特性。通过施加脉冲(±20V,持续时间100ms)获得了该器件在耐久性和保持性方面的存储操作,结果表明该器件在高达100次编程/擦除(P/E)循环时具有高度稳定的耐久性,并且在长达10s的时间内具有可靠的保持时间。所提出的NVM器件由于具有大存储窗口、稳定的耐久性和高保持时间等特性,为未来的非易失性存储技术提供了一种出色的方法。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/71be/8146410/286ca235c39b/nanomaterials-11-01101-g001.jpg

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