Anisimov Daniil S, Chekusova Victoria P, Trul Askold A, Abramov Anton A, Borshchev Oleg V, Agina Elena V, Ponomarenko Sergey A
Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences, Profsoyuznaya str. 70, 117393, Moscow, Russian Federation.
Printeltech LLC, Profsoyuznaya str. 70, 117393, Moscow, Russian Federation.
Sci Rep. 2021 May 21;11(1):10683. doi: 10.1038/s41598-021-88569-x.
Modern solid-state gas sensors approaching ppb-level limit of detection open new perspectives for process control, environmental monitoring and exhaled breath analysis. Organic field-effect transistors (OFETs) are especially promising for gas sensing due to their outstanding sensitivities, low cost and small power consumption. However, they suffer of poor selectivity, requiring development of cross-selective arrays to distinguish analytes, and environmental instability, especially in humid air. Here we present the first fully integrated OFET-based electronic nose with the whole sensor array located on a single substrate. It features down to 30 ppb limit of detection provided by monolayer thick active layers and operates in air with up to 95% relative humidity. By means of principal component analysis, it is able to discriminate toxic air pollutants and monitor meat product freshness. The approach presented paves the way for developing affordable air sensing networks for the Internet of Things.
现代固态气体传感器接近十亿分之一级别的检测极限,为过程控制、环境监测和呼气分析开辟了新的前景。有机场效应晶体管(OFET)因其出色的灵敏度、低成本和低功耗,在气体传感方面特别有前景。然而,它们存在选择性差的问题,需要开发交叉选择性阵列来区分分析物,并且存在环境不稳定性,尤其是在潮湿空气中。在此,我们展示了首个完全集成的基于OFET的电子鼻,整个传感器阵列位于单个基板上。它具有由单层厚有源层提供的低至30 ppb的检测极限,并且在相对湿度高达95%的空气中运行。通过主成分分析,它能够区分有毒空气污染物并监测肉类产品的新鲜度。所提出的方法为开发适用于物联网的经济实惠的空气传感网络铺平了道路。