Abdullah C K, Ismail I, Nurul Fazita M R, Olaiya N G, Nasution H, Oyekanmi A A, Nuryawan Arif, H P S Abdul Khalil
School of Industrial Technology, Universiti Sains Malaysia, Penang 11800, Malaysia.
Physics Department, Mathematics and Natural Sciences Faculty, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia.
Polymers (Basel). 2021 May 17;13(10):1615. doi: 10.3390/polym13101615.
The effect of incorporating different loadings of oil palm bio-ash nanoparticles from agriculture waste on the properties of phenol-formaldehyde resin was investigated in this study. The bio-ash filler was used to enhance the performance of phenol-formaldehyde nanocomposites. Phenol-formaldehyde resin filled with oil palm bio-ash nanoparticles was prepared via the in-situ polymerization process to produce nanocomposites. The transmission electron microscope and particle size analyzer result revealed that oil palm bio-ash nanoparticles had a spherical geometry of 90 nm. Furthermore, X-ray diffraction results confirmed the formation of crystalline structure in oil palm bio-ash nanoparticles and phenol-formaldehyde nanocomposites. The thermogravimetric analysis indicated that the presence of oil palm bio-ash nanoparticles enhanced the thermal stability of the nanocomposites. The presence of oil palm bio-ash nanoparticles with 1% loading in phenol-formaldehyde resin enhanced the internal bonding strength of plywood composites. The scanning electron microscope image revealed that phenol-formaldehyde nanocomposites morphology had better uniform distribution and dispersion with 1% oil palm bio-ash nanoparticle loading than other phenol-formaldehyde nanocomposites produced. The nanocomposite has potential use in the development of particle and panel board for industrial applications.
本研究考察了将不同含量的农业废弃物油棕生物灰纳米颗粒掺入酚醛树脂中对其性能的影响。生物灰填料用于提高酚醛纳米复合材料的性能。通过原位聚合法制备了填充油棕生物灰纳米颗粒的酚醛树脂,以生产纳米复合材料。透射电子显微镜和粒度分析仪结果显示,油棕生物灰纳米颗粒呈球形,直径为90纳米。此外,X射线衍射结果证实了油棕生物灰纳米颗粒和酚醛纳米复合材料中晶体结构的形成。热重分析表明,油棕生物灰纳米颗粒的存在提高了纳米复合材料的热稳定性。在酚醛树脂中加入1%的油棕生物灰纳米颗粒提高了胶合板复合材料的内部结合强度。扫描电子显微镜图像显示,与其他制备的酚醛纳米复合材料相比,含1%油棕生物灰纳米颗粒的酚醛纳米复合材料形态具有更好的均匀分布和分散性。该纳米复合材料在工业应用的颗粒板和面板开发中具有潜在用途。