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油棕废弃物纳米颗粒对混合胶合板生物复合材料性能及表征的增强作用

Enhancement of Oil Palm Waste Nanoparticles on the Properties and Characterization of Hybrid Plywood Biocomposites.

作者信息

Nuryawan Arif, Abdullah C K, Hazwan Che Mohamad, Olaiya N G, Yahya Esam Bashir, Risnasari Iwan, Masruchin Nanang, Baharudin M S, Khalid Hasmawi, Abdul Khalil H P S

机构信息

Department of Forest Products Technology, Faculty of Forestry, Universitas Sumatera Utara, Medan 20155, Indonesia.

School of Industrial Technology, Universiti Sains Malaysia, Penang 11800, Malaysia.

出版信息

Polymers (Basel). 2020 Apr 27;12(5):1007. doi: 10.3390/polym12051007.

Abstract

Using oil palm trunk (OPT) layered with empty fruit bunch (EFB), so-called hybrid plywood enhanced with palm oil ash nanoparticles, with phenol-formaldehyde (PF) resin as a binder, was produced in this study. The phenol-formaldehyde (PF) resins filled with different loading of oil palm ash (OPA) nanoparticles were prepared and used as glue for layers of the oil palm trunk (OPT) veneer and empty fruit bunch fibre mat. The resulting hybrid plywood produced was characterised. The physical, mechanical, thermal, and morphological properties of the hybrid plywood panels were investigated. The results obtained showed that the presence of OPA nanoparticles significantly affected the physical, mechanical, and thermal properties of the plywood panels. Significant improvements in dimension from water absorption and thickness swelling experiments were obtained for the plywood panels with the highest OPA nanoparticles loading in PF resin. The mechanical properties indicated that plywood composites showed improvement in flexural, shear, and impact properties until a certain loading of OPA nanoparticles in PF resin. Fracture surface morphology also showed the effectiveness of OPA nanoparticles in the reduction of layer breakage due to force and stress distribution. The thermal stability performance showed that PF filled OPA nanoparticles contributed to the thermal stability of the plywood panels. Therefore, the results obtained in this study showed that OPA nanoparticles certainly improved the characteristic of the hybrid plywood.

摘要

本研究采用油棕树干(OPT)与空果串(EFB)层叠,并以棕榈油灰纳米颗粒增强,以酚醛(PF)树脂为粘合剂,制备了所谓的混合胶合板。制备了填充不同含量油棕灰(OPA)纳米颗粒的酚醛(PF)树脂,并将其用作油棕树干(OPT)单板层和空果串纤维毡的胶水。对所得混合胶合板进行了表征。研究了混合胶合板面板的物理、机械、热学和形态学性能。所得结果表明,OPA纳米颗粒的存在显著影响了胶合板面板的物理、机械和热学性能。在PF树脂中OPA纳米颗粒含量最高的胶合板面板,在吸水率和厚度膨胀实验中的尺寸有显著改善。力学性能表明,胶合板复合材料在PF树脂中OPA纳米颗粒达到一定含量之前,其弯曲、剪切和冲击性能有所改善。断裂表面形态也显示了OPA纳米颗粒在减少因力和应力分布导致的层间断裂方面的有效性。热稳定性性能表明,填充OPA纳米颗粒的PF有助于胶合板面板的热稳定性。因此,本研究所得结果表明,OPA纳米颗粒确实改善了混合胶合板的特性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/831c/7284790/da2d45b71eb6/polymers-12-01007-g001.jpg

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