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制备条件对机械制备的天然丝网膜和无纺布结构与性能的影响

Effects of Fabrication Conditions on Structure and Properties of Mechanically Prepared Natural Silk Web and Non-Woven Fabrics.

作者信息

Bae Yeon-Su, Um In-Chul

机构信息

Department of Biofibers and Biomaterials Science, Kyungpook National University, Daegu 41566, Korea.

Institute of Agricultural Science and Technology, Kyungpook National University, Daegu 41566, Korea.

出版信息

Polymers (Basel). 2021 May 14;13(10):1578. doi: 10.3390/polym13101578.

Abstract

In this study, natural silk web and natural silk non-woven fabric were prepared mechanically using the binding character of the sericin in silk. The effect of process variables on the preparation, structure, and properties of the silk web and the non-woven fabric was examined. The reeling velocity affected the morphology and mechanical properties of the web but had almost no influence on the crystalline structure of the silk. From the viewpoint of reel-ability and the mechanical properties (work of rupture) of silk web, a reeling velocity of 39.2 m/min represented the optimal processing velocity. The porosity and swelling ratio of the silk web decreased slightly with increasing reeling velocity. Furthermore, the reeling bath temperature had a significant effect on the reel-ability of silk filaments from a silkworm cocoon. Bath temperatures ≥50 °C yielded good reel-ability (>900 m reeling length). The porosity, swelling ratio in water, and mechanical properties of the silk web and silk non-woven fabric changed only slightly with the reeling bath temperature but changed significantly with the hot press treatment. The hot-pressed silk web (i.e., silk non-woven fabric) exhibited higher tensile strength as well as lower elongation at break, porosity, and swelling ratio than the silk web.

摘要

在本研究中,利用蚕丝中丝胶的粘结特性,通过机械方法制备了天然丝网膜和天然丝无纺布。研究了工艺变量对丝网膜和无纺布的制备、结构及性能的影响。缫丝速度影响丝网膜的形态和力学性能,但对蚕丝的晶体结构几乎没有影响。从丝网膜的可缫性和力学性能(断裂功)来看,39.2 m/min的缫丝速度代表了最佳加工速度。丝网膜的孔隙率和溶胀率随缫丝速度的增加而略有下降。此外,缫丝浴温度对蚕茧中丝纤维的可缫性有显著影响。浴温≥50°C时可获得良好的可缫性(缫丝长度>900 m)。丝网膜和丝无纺布的孔隙率、水溶胀率及力学性能随缫丝浴温度变化不大,但随热压处理变化显著。热压丝网膜(即丝无纺布)比丝网膜表现出更高的拉伸强度以及更低的断裂伸长率、孔隙率和溶胀率。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c254/8156477/2c230021abcb/polymers-13-01578-g001.jpg

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