邻位季碳立体中心的催化对映选择性构建。
Catalytic enantioselective construction of vicinal quaternary carbon stereocenters.
作者信息
Zhou Feng, Zhu Lei, Pan Bo-Wen, Shi Yang, Liu Yun-Lin, Zhou Jian
机构信息
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Shanghai Engineering Research Center of Molecular Therapeutics and New Drug Development, East China Normal University Shanghai 200062 P. R. China
School of Chemistry and Materials Science, Hubei Engineering University Hubei 432000 P. R. China
出版信息
Chem Sci. 2020 Jul 28;11(35):9341-9365. doi: 10.1039/d0sc03249b.
This review summarizes the advances in the catalytic enantioselective construction of vicinal quaternary carbon stereocenters, introduces major synthetic strategies and discusses their advantages and limitations, highlights the application of known protocols in the total synthesis of natural products, and outlines the synthetic opportunities.
本综述总结了连位季碳立体中心的催化对映选择性构建方面的进展，介绍了主要的合成策略并讨论了其优缺点，重点阐述了已知方法在天然产物全合成中的应用，并概述了合成机会。
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