Arhangelskis Mihails, Bučar Dejan-Krešimir, Bordignon Simone, Chierotti Michele R, Stratford Samuel A, Voinovich Dario, Jones William, Hasa Dritan
Faculty of Chemistry, University of Warsaw 1 Pasteura Street Warsaw 02-093 Poland.
Department of Chemistry, University College London 20 Gordon Street London WC1H 0AJ UK
Chem Sci. 2021 Jan 20;12(9):3264-3269. doi: 10.1039/d0sc05071g.
We demonstrate that liquid additives can exert inhibitive or prohibitive effects on the mechanochemical formation of multi-component molecular crystals, and report that certain additives unexpectedly prompt the dismantling of such solids into physical mixtures of their constituents. Computational methods were employed in an attempt to identify possible reasons for these previously unrecognised effects of liquid additives on mechanochemical transformations.
我们证明了液体添加剂可对多组分分子晶体的机械化学形成产生抑制或阻止作用，并报告了某些添加剂意外地促使此类固体分解为其组分的物理混合物。我们采用计算方法来试图确定液体添加剂对机械化学转化产生这些先前未被认识到的影响的可能原因。
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