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具有成本效益的、高产量生产生物模板催化管状微马达作为用于水处理的自驱动微型清洁器。

Cost-Effective, High-Yield Production of Biotemplated Catalytic Tubular Micromotors as Self-Propelled Microcleaners for Water Treatment.

作者信息

Chen Ling, Yuan Hao, Chen Shuqin, Zheng Chan, Wu Xiukai, Li Ziqiao, Liang Chunyan, Dai Pinqiang, Wang Qianting, Ma Xing, Yan Xiaohui

机构信息

School of Materials Science and Engineering, Fujian University of Technology, Fuzhou 350108, China.

State Key Laboratory of Molecular Vaccinology and Molecular Diagnostics & Center for Molecular Imaging and Translational Medicine, School of Public Health, Xiamen University, Xiamen, Fujian 361005, China.

出版信息

ACS Appl Mater Interfaces. 2021 Jul 7;13(26):31226-31235. doi: 10.1021/acsami.1c03595. Epub 2021 Jun 27.

Abstract

Micro/nano-motors (MNMs) that combine attributes of miniaturization and self-propelled swimming mobility have been explored for efficient environmental remediation in the past decades. However, their progresses in practical applications are now subject to several critical issues including a complicated fabrication process, low production yield, and high material cost. Herein, we propose a biotemplated catalytic tubular micromotor consisting of a kapok fiber (KF, abundant in nature) matrix and manganese dioxide nanoparticles (MnO NPs) deposited on the outer and inner walls of the KF and demonstrate its applications for rapid removal of methylene blue (MB) in real-world wastewater. The fabrication is straightforward via dipping the KF into a potassium permanganate (KMnO) solution, featured with high yield and low cost. The distribution and amount of MnO can be easily controlled by varying the dipping time. The obtained motors are actuated and propelled by oxygen (O) bubbles generated from MnO-triggered catalytic decomposition of hydrogen peroxide (HO), with the highest speed at 615 μm/s (i.e., 6 body length per second). To enhance decontamination efficacy and also enable magnetic navigation/recycling, magnetite nanoparticles (FeO NPs) are adsorbed onto such motors via an electrostatic effect. Both the FeO-induced Fenton reaction and hydroxyl radicals from MnO-catalyzed HO decomposition can account for the MB removal (or degradation). Results of this study, taken together, provide a cost-effective approach to achieve high-yield production of the MNMs, suggesting an automatous microcleaner able to perform practical wastewater treatment.

摘要

在过去几十年中,人们一直在探索结合了小型化和自驱动游动特性的微纳马达(MNMs),用于高效的环境修复。然而,它们在实际应用中的进展目前受到几个关键问题的制约,包括复杂的制造工艺、低产量和高材料成本。在此,我们提出一种生物模板催化管状微马达,它由木棉纤维(KF,自然界中含量丰富)基质和沉积在KF内外壁上的二氧化锰纳米颗粒(MnO NPs)组成,并展示了其在实际废水中快速去除亚甲基蓝(MB)的应用。通过将KF浸入高锰酸钾(KMnO)溶液中即可直接制备,具有高产率和低成本的特点。通过改变浸渍时间可以很容易地控制MnO的分布和数量。所获得的微马达由MnO引发的过氧化氢(HO)催化分解产生的氧气(O)气泡驱动和推进,最高速度为615μm/s(即每秒6个体长)。为了提高去污效果并实现磁导航/回收,通过静电作用将磁铁矿纳米颗粒(FeO NPs)吸附到这种微马达上。FeO诱导的芬顿反应和MnO催化的HO分解产生的羟基自由基都可以解释MB的去除(或降解)。综合这项研究的结果,提供了一种经济有效的方法来实现MNMs的高产率生产,表明一种能够进行实际废水处理的自动微型清洁器。

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