Jarzębska Anna, Maj Łukasz, Bieda Magdalena, Chulist Robert, Wojtas Daniel, Wątroba Maria, Janus Karol, Rogal Łukasz, Sztwiertnia Krzysztof
Institute of Metallurgy and Materials Science, Polish Academy of Sciences, 30-059 Krakow, Poland.
Faculty of Physics and Applied Computer Science, AGH University of Science and Technology, 30-059 Krakow, Poland.
Materials (Basel). 2021 Jun 23;14(13):3483. doi: 10.3390/ma14133483.
High plasticity of bioabsorbable stents, either cardiac or ureteral, is of great importance in terms of implants' fabrication and positioning. Zn-Cu constitutes a promising group of materials in terms of feasible deformation since the superplastic effect has been observed in them, yet its origin remains poorly understood. Therefore, it is crucial to inspect the microstructural evolution of processed material to gain an insight into the mechanisms leading to such an extraordinary property. Within the present study, cold-rolled Zn-Cu alloys, i.e., Zn with addition of 1 wt.% and 5 wt.% of Cu, have been extensively investigated using scanning electron microscopy as well as transmission electron microscopy, so as to find out the possible explanation of superior plasticity of the Zn-Cu alloys. It has been stated that the continuous dynamic recrystallization has a tremendous impact on superior plasticity reported for Zn-1Cu alloy processed by rolling to 90% of reduction rate. The effect might be supported by static recrystallization, provoking grain growth and thereby yielding non-homogeneous microstructures. Such heterogeneous microstructure enables better formability since it increases the mean free path for dislocation movement.
生物可吸收支架,无论是心脏支架还是输尿管支架,其高可塑性在植入物的制造和定位方面都非常重要。就可行的变形而言,锌铜构成了一组有前景的材料,因为在其中观察到了超塑性效应,但其起源仍知之甚少。因此,检查加工材料的微观结构演变对于深入了解导致这种非凡性能的机制至关重要。在本研究中,使用扫描电子显微镜和透射电子显微镜对冷轧锌铜合金,即添加了1 wt.%和5 wt.%铜的锌进行了广泛研究,以找出锌铜合金具有优异可塑性的可能解释。据称,连续动态再结晶对通过轧制至90%的压下率加工的Zn-1Cu合金所报道的优异可塑性有巨大影响。静态再结晶可能会支持这种效应,引发晶粒生长,从而产生不均匀的微观结构。这种不均匀的微观结构能够实现更好的可成形性,因为它增加了位错运动的平均自由程。