水热法制备镧系金属-有机框架用于高灵敏度检测呋喃妥因和 l-酪氨酸。
Solvothermal Preparation of a Lanthanide Metal-Organic Framework for Highly Sensitive Discrimination of Nitrofurantoin and l-Tyrosine.
机构信息
Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, College of Chemistry, Tianjin Normal University, 393 Binshui West Road, Tianjin 300387, China.
Department of Chemistry and Key Laboratory of Advanced Energy Materials Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China.
出版信息
Molecules. 2021 Jun 16;26(12):3673. doi: 10.3390/molecules26123673.
Metal-organic frameworks (MOFs) have been rapidly developed for their broad applications in many different chemistry and materials fields. In this work, a multi-dentate building block 5-(4-(tetrazol-5-yl)phenyl)-isophthalic acid (HL) containing tetrazole and carbolxylate moieties was employed for the synthesis of a two-dimensional (2D) lanthanide MOF [La(HL)(DMF)(NO)] (DMF = ,-dimethylformamide) () under solvothermal condition. The fluorescent sensing application of was investigated. exhibits high sensitivity recognition for antibiotic nitrofurantoin (K: 3.0 × 10 M and detection limit: 17.0 μM) and amino acid l-tyrosine (K: 1.4 × 10 M and detection limit: 3.6 μM). This work provides a feasible detection platform of 2D MOFs for highly sensitive discrimination of antibiotics and amino acids.
金属-有机框架（MOFs）因其在许多不同化学和材料领域的广泛应用而得到了快速发展。在这项工作中，使用了一种多齿建筑块 5-(4-(四唑-5-基)苯基）-间苯二甲酸（HL），其中含有四唑和羧酸酯部分，用于合成二维（2D）镧系 MOF [La(HL)(DMF)(NO)]（DMF =,-二甲基甲酰胺）()在溶剂热条件下。研究了 的荧光传感应用。 对抗生素呋喃妥因（K：3.0×10 M，检测限：17.0 μM）和氨基酸 l-酪氨酸（K：1.4×10 M，检测限：3.6 μM）具有高灵敏度识别能力。这项工作为 2D MOFs 提供了一个可行的检测平台，用于高度敏感地区分抗生素和氨基酸。
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