Hydrogen Evolution Electrocatalyst Design: Turning Inert Gold into Active Catalyst by Atomically Precise Nanochemistry.

Electrocatalytic hydrogen evolution reaction (HER) holds promise in the renewable clean energy scheme. Crystalline Au and Ag are, however, poor in catalyzing HER, and the ligands on colloidal nanoparticles are generally another disadvantage. Herein, we report a thiolate (SR)-protected AuAg(SR) nanocluster with low coverage of ligands and a core composed of three icosahedral () units for catalyzing HER efficiently. This trimeric structure, together with the monomeric Au(SR) and dimeric Au(SR), constitutes a unique series, providing an opportunity for revealing the correlation between the catalytic properties and the catalyst's structure. The AuAg(SR) surprisingly exhibits high catalytic activity at lower overpotentials for HER due to its low ligand-to-metal ratio, low-coordinated Au atoms and unfilled superatomic orbitals. The current density of AuAg(SR) at -0.3 V vs RHE is 3.8 and 5.1 times that of Au(SR) and Au(SR), respectively. Density functional theory (DFT) calculations reveal lower hydrogen binding energy and higher electron affinity of AuAg(SR) for an energetically feasible HER pathway. Our findings provide a new strategy for constructing highly active catalysts from inert metals by pursuing atomically precise nanoclusters and controlling their geometrical and electronic structures.