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大气中有机污染物在亚得里亚海中部地区的污染水平和沉积过程:时间变化和来源识别。

Pollution levels and deposition processes of airborne organic pollutants over the central Adriatic area: Temporal variabilities and source identification.

机构信息

Institute for Medical Research and Occupational Health, 10000 Zagreb, Croatia.

Institute for Medical Research and Occupational Health, 10000 Zagreb, Croatia.

出版信息

Mar Pollut Bull. 2021 Nov;172:112873. doi: 10.1016/j.marpolbul.2021.112873. Epub 2021 Aug 21.

DOI:10.1016/j.marpolbul.2021.112873
PMID:34428622
Abstract

First data on polycyclic aromatic hydrocarbons (PAHs) and nitro-aromatic compounds (NACs) in aerosols as well as of PAHs, polychlorinated biphenyls (PCBs) and NACs in bulk and wet atmospheric deposition samples were simultaneously obtained during 6-month-long field campaign at the costal central Adriatic area. Special attention was given to open-fire biomass burning episodes as extreme events common for the overall Mediterranean coastal area in order to gain a better understanding of the atmospheric variabilities and potential sources of trace organic pollutants in coastal environments. Diesel and gasoline combustion related to land and maritime traffic as well as occasional open-fire episodes (forest fires) were found to be the dominant pollution sources of PAHs in PM particles. NACs were determined almost exclusively in samples affected by biomass burning episodes. Open-fire episodes had a strong contribution to the overall NACs atmospheric deposition fluxes. Several chlorinated congeners of PCBs were predominantly contributed in deposition samples.

摘要

在亚得里亚海中部沿海地区进行了为期 6 个月的野外考察,期间同时获得了气溶胶中多环芳烃(PAHs)和硝基芳烃化合物(NACs)以及颗粒物和湿大气沉降样品中 PAHs、多氯联苯(PCBs)和 NACs 的首批数据。特别关注露天燃烧生物质的事件,因为它们是整个地中海沿海地区的常见极端事件,以便更好地了解沿海环境中痕量有机污染物的大气变化和潜在来源。研究发现,与陆地和海上交通有关的柴油和汽油燃烧以及偶尔的露天燃烧事件(森林火灾)是 PM 颗粒物中 PAHs 的主要污染源。NACs 几乎仅存在于受生物质燃烧事件影响的样品中。露天燃烧事件对 NACs 的大气沉积通量有很大的贡献。在沉积样品中主要存在几种氯代 PCBs 同系物。

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