• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

高性能复合水凝胶的制备：增强亲水改性废橡胶粉。

Preparation of High-Performance Composite Hydrogel Reinforced by Hydrophilic Modified Waste Rubber Powder.

机构信息

State Key Laboratory of Polymer Materials Engineering, College of Polymer Science and Engineering, Sichuan University, Chengdu 610065, China.

Exploration and Development Research Institute, Shengli Oilfield Company, SINOPEC, Dongying 257015, China.

出版信息

Molecules. 2021 Aug 7;26(16):4788. doi: 10.3390/molecules26164788.

DOI:10.3390/molecules26164788
PMID:34443376
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8401038/
Abstract

In order to reduce the environmental pollution caused by waste rubber and to realize the recycling of resources, we proposed a facile method for the hydrophilic modification of waste rubber powder (HRP) and used it to reinforce a composite hydrogel. In the presence of toluene, dibenzoyl peroxide (BPO) diffused into the waste rubber powder. After the solvent was removed, BPO was adsorbed in the rubber powder, which was used to initiate the grafting polymerization of the acrylamide monomer on the rubber-water interface. As a result, the polyacrylamide (PAM) molecular chains were grafted onto the surface of the rubber powder to realize hydrophilic modification. The success of the grafting modification was confirmed by FTIR, contact angle testing, and thermogravimetric analysis. The hydrophilic modified waste rubber powder was used to reinforce the PAM hydrogel. Mechanical tests showed that the tensile strength and elongation at the break of the composite hydrogel reached 0.46 MPa and 1809%, respectively, which was much higher than those of pure PAM hydrogel. Such a phenomenon indicates that the waste rubber particles had a strengthening effect.

摘要

为了减少废橡胶造成的环境污染并实现资源的循环利用，我们提出了一种简便的废橡胶粉（HRP）亲水改性方法，并将其用于增强复合水凝胶。在甲苯存在的情况下，过氧化二苯甲酰（BPO）扩散到废橡胶粉中。除去溶剂后，BPO 被吸附在橡胶粉末中，用于引发丙烯酰胺单体在橡胶-水界面上的接枝聚合。结果，聚丙烯酰胺（PAM）分子链接枝到橡胶粉末表面，实现亲水改性。接枝改性的成功通过傅里叶变换红外光谱（FTIR）、接触角测试和热重分析得到了证实。亲水改性废橡胶粉用于增强 PAM 水凝胶。力学测试表明，复合水凝胶的拉伸强度和断裂伸长率分别达到 0.46 MPa 和 1809%，远高于纯 PAM 水凝胶。这种现象表明废橡胶颗粒具有增强效果。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc71/8401038/5ac9ce07be10/molecules-26-04788-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc71/8401038/50c56df4415f/molecules-26-04788-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc71/8401038/95b16fd732cc/molecules-26-04788-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc71/8401038/47926613ab08/molecules-26-04788-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc71/8401038/f1913a0ca2bd/molecules-26-04788-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc71/8401038/0d9fa3bd6175/molecules-26-04788-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc71/8401038/33c8914dd791/molecules-26-04788-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc71/8401038/9ddd2d090b35/molecules-26-04788-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc71/8401038/48b0a7897d75/molecules-26-04788-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc71/8401038/5ac9ce07be10/molecules-26-04788-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc71/8401038/50c56df4415f/molecules-26-04788-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc71/8401038/95b16fd732cc/molecules-26-04788-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc71/8401038/47926613ab08/molecules-26-04788-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc71/8401038/f1913a0ca2bd/molecules-26-04788-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc71/8401038/0d9fa3bd6175/molecules-26-04788-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc71/8401038/33c8914dd791/molecules-26-04788-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc71/8401038/9ddd2d090b35/molecules-26-04788-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc71/8401038/48b0a7897d75/molecules-26-04788-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc71/8401038/5ac9ce07be10/molecules-26-04788-g009.jpg

相似文献

1
Preparation of High-Performance Composite Hydrogel Reinforced by Hydrophilic Modified Waste Rubber Powder.高性能复合水凝胶的制备：增强亲水改性废橡胶粉。
Molecules. 2021 Aug 7;26(16):4788. doi: 10.3390/molecules26164788.
2
[Preparation and Performance Evaluation of Polyacrylamide Hydrogel Coating on the Surface of Silicone Rubber Nasogastric Tube].[硅橡胶鼻胃管表面聚丙烯酰胺水凝胶涂层的制备及性能评价]
Sichuan Da Xue Xue Bao Yi Xue Ban. 2023 Jul;54(4):782-787. doi: 10.12182/20230760205.
3
Evaluation of rubber powder waste as reinforcement of the polyurethane derived from castor oil.评估橡胶粉末废料作为蓖麻油衍生的聚氨酯的增强材料。
Waste Manag. 2020 Oct;116:131-139. doi: 10.1016/j.wasman.2020.07.032. Epub 2020 Aug 12.
4
Preparation of Poly(acrylic acid--acrylamide)- Deproteinized Natural Rubber and Its Effect on the Properties of Natural Rubber/Silica Composites.聚（丙烯酸-丙烯酰胺）-脱蛋白天然橡胶的制备及其对天然橡胶/二氧化硅复合材料性能的影响。
Polymers (Basel). 2022 Oct 29;14(21):4602. doi: 10.3390/polym14214602.
5
Thermal and Mechanical Properties of Concrete Incorporating Silica Fume and Waste Rubber Powder.掺硅灰和废橡胶粉混凝土的热性能和力学性能
Polymers (Basel). 2022 Nov 11;14(22):4858. doi: 10.3390/polym14224858.
6
Recycling of waste tyre rubber into oil absorbent.将废旧轮胎橡胶回收制成吸油材料。
Waste Manag. 2009 Jan;29(1):355-9. doi: 10.1016/j.wasman.2008.03.002. Epub 2008 May 1.
7
Enhanced Storage Stability and Rheological Properties of Asphalt Modified by Activated Waste Rubber Powder.活化废橡胶粉改性沥青的储存稳定性和流变性能增强
Materials (Basel). 2021 May 20;14(10):2693. doi: 10.3390/ma14102693.
8
Characterization of the properties of thermoplastic elastomers containing waste rubber tire powder.含废旧橡胶轮胎粉末的热塑性弹性体性能表征
Waste Manag. 2009 May;29(5):1480-5. doi: 10.1016/j.wasman.2008.10.004. Epub 2008 Dec 12.
9
Determining engineering properties of ultra-high-performance fiber-reinforced geopolymer concrete modified with different waste materials.确定不同废料改性超高韧性纤维增强地质聚合物混凝土的工程特性。
PLoS One. 2023 May 22;18(5):e0285692. doi: 10.1371/journal.pone.0285692. eCollection 2023.
10
Physical, rheological and microscopic properties of AAT nanomaterial/crumb rubber powder composite-modified asphalt and SBS-modified asphalt.AAT 纳米材料/橡胶粉颗粒复合改性沥青和 SBS 改性沥青的物理、流变学和微观性能。
PLoS One. 2024 Jan 11;19(1):e0284813. doi: 10.1371/journal.pone.0284813. eCollection 2024.

引用本文的文献

1
A new concept of biocatalytic synthesis of acrylic monomers for obtaining water-soluble acrylic heteropolymers.一种用于制备水溶性丙烯酸杂聚物的丙烯酸单体生物催化合成的新概念。
Metab Eng Commun. 2023 Dec 19;18:e00231. doi: 10.1016/j.mec.2023.e00231. eCollection 2024 Jun.

本文引用的文献

1
Mechanically tough and highly stretchable poly(acrylic acid) hydrogel cross-linked by 2D graphene oxide.由二维氧化石墨烯交联的机械坚韧且高度可拉伸的聚丙烯酸水凝胶。
RSC Adv. 2020 Mar 17;10(18):10949-10958. doi: 10.1039/d0ra00678e. eCollection 2020 Mar 11.
2
Rubber Recycling: Mending the Interface between Ground Rubber Particles and Virgin Rubber.橡胶回收：修复胶粉颗粒与原生橡胶之间的界面
ACS Appl Mater Interfaces. 2020 Oct 21;12(42):47957-47965. doi: 10.1021/acsami.0c13722. Epub 2020 Oct 7.
3
Dual pH-Responsive Hydrogel Actuator for Lipophilic Drug Delivery.
用于脂溶性药物递送的双 pH 响应水凝胶驱动器。
ACS Appl Mater Interfaces. 2020 Mar 11;12(10):12010-12017. doi: 10.1021/acsami.9b21713. Epub 2020 Feb 25.
4
Waste Rubber Recycling: A Review on the Evolution and Properties of Thermoplastic Elastomers.废橡胶回收利用：热塑性弹性体的发展历程与性能综述
Materials (Basel). 2020 Feb 8;13(3):782. doi: 10.3390/ma13030782.
5
Mechanically and Electronically Robust Transparent Organohydrogel Fibers.机械和电子性能稳定的透明有机水凝胶纤维。
Adv Mater. 2020 Feb;32(8):e1906994. doi: 10.1002/adma.201906994. Epub 2020 Jan 19.
6
A self-assembled RNA-triple helix hydrogel drug delivery system targeting triple-negative breast cancer.一种针对三阴性乳腺癌的自组装 RNA 三螺旋水凝胶药物递送系统。
J Mater Chem B. 2020 Apr 29;8(16):3527-3533. doi: 10.1039/c9tb01610d.
7
Preparation of Octadecyl Amine Grafted over Waste Rubber Powder (ODA-WRP) and Properties of Its Incorporation in SBS-Modified Asphalt.废胶粉接枝十八胺（ODA-WRP）的制备及其在SBS改性沥青中的掺入性能
Polymers (Basel). 2019 Apr 11;11(4):665. doi: 10.3390/polym11040665.
8
Hydrogel as an alternative structure for food packaging systems.水凝胶作为食品包装系统的替代结构。
Carbohydr Polym. 2019 Feb 1;205:106-116. doi: 10.1016/j.carbpol.2018.10.006. Epub 2018 Oct 6.
9
Self-recovery magnetic hydrogel with high strength and toughness using nanofibrillated cellulose as a dispersing agent and filler.使用纳米纤维纤维素作为分散剂和填充剂的高强度和高韧性自恢复磁水凝胶。
Carbohydr Polym. 2018 Sep 15;196:82-91. doi: 10.1016/j.carbpol.2018.05.023. Epub 2018 May 15.
10
Potential of activated carbon from waste rubber tire for the adsorption of phenolics: effect of pre-treatment conditions.废橡胶轮胎活性炭对酚类物质吸附的潜力：预处理条件的影响。
J Colloid Interface Sci. 2014 Mar 1;417:420-30. doi: 10.1016/j.jcis.2013.11.067. Epub 2013 Dec 4.