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高电流密度下的纳秒脉冲钙钛矿发光二极管

Nanosecond-Pulsed Perovskite Light-Emitting Diodes at High Current Density.

作者信息

Zhao Lianfeng, Roh Kwangdong, Kacmoli Sara, Al Kurdi Khaled, Liu Xiao, Barlow Stephen, Marder Seth R, Gmachl Claire, Rand Barry P

机构信息

Department of Electrical Engineering, Princeton University, Princeton, NJ, 08544, USA.

School of Chemistry and Biochemistry, Center for Organic Electronics, Georgia Institute of Technology, Atlanta, GA, 30332-0400, USA.

出版信息

Adv Mater. 2021 Nov;33(44):e2104867. doi: 10.1002/adma.202104867. Epub 2021 Sep 3.

Abstract

While metal-halide perovskite light-emitting diodes (PeLEDs) hold the potential for a new generation of display and lighting technology, their slow operation speed and response time limit their application scope. Here, high-speed PeLEDs driven by nanosecond electrical pulses with a rise time of 1.2 ns are reported with a maximum radiance of approximately 480 kW sr  m at 8.3 kA cm , and an external quantum efficiency (EQE) of 1% at approximately 10 kA cm , through improved device configuration designs and material considerations. Enabled by the fast operation of PeLEDs, the temporal response provides access to transient charge carrier dynamics under electrical excitation, revealing several new electroluminescence quenching pathways. Finally, integrated distributed feedback (DFB) gratings are explored, which facilitate more directional light emission with a maximum radiance of approximately 1200 kW sr m at 8.5 kA cm , a more than two-fold enhancement to forward radiation output.

摘要

虽然金属卤化物钙钛矿发光二极管(PeLEDs)具有应用于新一代显示和照明技术的潜力,但其缓慢的运行速度和响应时间限制了它们的应用范围。在此,通过改进器件结构设计和材料选择,报道了由上升时间为1.2 ns的纳秒电脉冲驱动的高速PeLEDs,在8.3 kA/cm²时最大辐射亮度约为480 kW/(sr·m²),在约10 kA/cm²时外部量子效率(EQE)为1%。得益于PeLEDs的快速运行,其时间响应使得能够研究电激发下的瞬态电荷载流子动力学,揭示了几种新的电致发光猝灭途径。最后,探索了集成分布式反馈(DFB)光栅,其有助于实现更具方向性的光发射,在8.5 kA/cm²时最大辐射亮度约为1200 kW/(sr·m²),正向辐射输出提高了两倍多。

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