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用于辐射屏蔽的 GdxFeO(100-x)/PVA(x=0、5、10、20)复合膜的制备与表征。

Fabrication and characterization of GdxFeO(100-x) /PVA (x=0, 5, 10, 20) composite films for radiation shielding.

机构信息

Vocational School of Health Services, Dept. of Medical Imaging Techniques, Kahramanmaras Sutcu Imam Univ, Kahramanmaras, Turkey.

Vocational School of Health Services, Department of Opticianry, Kahramanmaraş Sütçu İmam University, Kahramanmaraş, Turkey.

出版信息

Appl Radiat Isot. 2021 Nov;177:109918. doi: 10.1016/j.apradiso.2021.109918. Epub 2021 Sep 1.

Abstract

Purpose of this study is to investigate effect of gadolinium (Gd) content of GdxFe2O3(100-x), (x = 0, 5, 10, 20) composite system on structural, thermal, optical and radiation protection of poly (vinyl alchool) PVA based nanocomposite film. In this study, Gd doped FeO nanopowders (with Gd = 0, 5, 10 and 20) were synthesized by spray pyrolysis method. The characterization of these powders have been obtained by using X-ray diffractometer (XRD), scanning electron microscopy (SEM), and Uv-vis spectrometer. After then, GdxFeO(100-x)/PVA (x = 0, 5, 10, 20) polymer composite systems were prepared by solution casting technique. The structural, thermal and optical properties of obtained polymer composites have been examined. The irradiation properties of 6 MeV energized X-ray via cLINAC to obtain radiation shielding performance of these different percentage (0, 5, 10, and 20%) Gd doped FeO PVA thin films were also investigated. By using obtained results, the Linear Attenuation Coefficient (LAC), Half Value Layer (HVL), Tenth Value Layer (TVL), Mass Attenuation Coefficient (MAC). Also, theoretically Z value have been calculated. According to all obtained results, it has been seen that the different percentages (0, 5, 10, and 20%) Gd doped FeO PVA thin films can be used as radiation shielding material.

摘要

本研究的目的是研究 GdxFe2O3(100-x)(x=0、5、10、20)复合体系中钆(Gd)含量对聚(乙烯醇)PVA 基纳米复合膜的结构、热、光和辐射防护性能的影响。在本研究中,通过喷雾热解法合成了 Gd 掺杂的 FeO 纳米粉末(Gd=0、5、10 和 20)。通过 X 射线衍射仪(XRD)、扫描电子显微镜(SEM)和 Uv-vis 分光光度计获得了这些粉末的特性。然后,通过溶液浇铸技术制备了 GdxFeO(100-x)/PVA(x=0、5、10、20)聚合物复合材料体系。研究了所得聚合物复合材料的结构、热和光学性能。还研究了通过 cLINAC 对 6 MeV 能量的 X 射线进行辐照,以获得这些不同百分比(0、5、10 和 20%)Gd 掺杂 FeO PVA 薄膜的辐射屏蔽性能。根据所得结果,计算了线性衰减系数(LAC)、半价层(HVL)、十分之一值层(TVL)、质量衰减系数(MAC)。此外,还理论上计算了 Z 值。根据所有的结果,可以看出不同百分比(0、5、10 和 20%)的 Gd 掺杂 FeO PVA 薄膜可用作辐射屏蔽材料。

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