Lazzarin Luca, Pasini Mariacecilia, Menna Enzo
Department of Chemical Sciences & INSTM, University of Padua, Via Marzolo 1, 35131 Padova, Italy.
Institute of Chemical Sciences and Technologies "G. Natta"-SCITEC, National Research Council, CNR-SCITEC, Via Corti 12, 20133 Milan, Italy.
Molecules. 2021 Aug 31;26(17):5286. doi: 10.3390/molecules26175286.
This review presents an overview of the use of organic functionalized carbon nanostructures (CNSs) in solar energy conversion schemes. Our attention was focused in particular on the contribution of organic chemistry to the development of new hybrid materials that find application in dye-sensitized solar cells (DSSCs), organic photovoltaics (OPVs), and perovskite solar cells (PSCs), as well as in photocatalytic fuel production, focusing in particular on the most recent literature. The request for new materials able to accompany the green energy transition that are abundant, low-cost, low-toxicity, and made from renewable sources has further increased the interest in CNSs that meet all these requirements. The inclusion of an organic molecule, thanks to both covalent and non-covalent interactions, in a CNS leads to the development of a completely new hybrid material able of combining and improving the properties of both starting materials. In addition to the numerical data, which unequivocally state the positive effect of the new hybrid material, we hope that these examples can inspire further research in the field of photoactive materials from an organic point of view.
本文综述了有机功能化碳纳米结构(CNSs)在太阳能转换方案中的应用概况。我们特别关注有机化学对新型混合材料开发的贡献,这些材料可应用于染料敏化太阳能电池(DSSCs)、有机光伏电池(OPVs)和钙钛矿太阳能电池(PSCs),以及光催化燃料生产,尤其关注最新文献。对能够伴随绿色能源转型的新材料的需求不断增加,这些材料需丰富、低成本、低毒性且由可再生资源制成,这进一步提高了人们对满足所有这些要求的CNSs的兴趣。由于共价和非共价相互作用,将有机分子纳入CNS会导致一种全新的混合材料的开发,这种材料能够结合并改善两种起始材料的性能。除了明确表明新型混合材料积极效果的数值数据外,我们希望这些例子能够从有机角度激发光活性材料领域的进一步研究。