Seroka Ntalane S, Taziwa Raymond, Khotseng Lindiwe
Department of Chemistry, University of the Western Cape, Robert Sobukwe Rd, Private Bag X17, Bellville 7535, South Africa.
Department of Applied Science, Faculty of Science Engineering and Technology, Walter Sisulu University, Old King William Town Road, Potsdam Site, East London 5200, South Africa.
Materials (Basel). 2022 Aug 3;15(15):5338. doi: 10.3390/ma15155338.
The demand for energy has been a global concern over the years due to the ever increasing population which still generate electricity from non-renewable energy sources. Presently, energy produced worldwide is mostly from fossil fuels, which are non-renewable sources and release harmful by-products that are greenhouses gases. The sun is considered a source of clean, renewable energy, and the most abundant. With silicon being the element most used for the direct conversion of solar energy into electrical energy, solar cells are the technology corresponding to the solution of the problem of energy on our planet. Solar cell fabrication has undergone extensive study over the past several decades and improvement from one generation to another. The first solar cells were studied and grown on silicon wafers, in particular single crystals that formed silicon-based solar cells. With the further development in thin films, dye-sensitized solar cells and organic solar cells have significantly enhanced the efficiency of the cell. The manufacturing cost and efficiency hindered further development of the cell, although consumers still have confidence in the crystalline silicon material, which enjoys a fair share in the market for photovoltaics. This present review work provides niche and prominent features including the benefits and prospects of the first (mono-poly-crystalline silicon), second (amorphous silicon and thin films), and third generation (quantum dots, dye synthesized, polymer, and perovskite) of materials evolution in photovoltaics.
多年来,由于人口不断增长,且仍在使用不可再生能源发电,能源需求一直是全球关注的问题。目前,全球生产的能源大多来自化石燃料,化石燃料是不可再生能源,会释放出作为温室气体的有害副产品。太阳被视为清洁、可再生能源的来源,且最为丰富。由于硅是最常用于将太阳能直接转化为电能的元素,太阳能电池是解决我们星球能源问题的相应技术。在过去几十年里,太阳能电池制造经历了广泛研究,并一代比一代有所改进。最早的太阳能电池是在硅片上研究和生长的,特别是形成硅基太阳能电池的单晶。随着薄膜技术的进一步发展,染料敏化太阳能电池和有机太阳能电池显著提高了电池效率。尽管消费者对晶体硅材料仍有信心,晶体硅材料在光伏市场中占有相当份额,但制造成本和效率阻碍了电池的进一步发展。本综述工作介绍了光伏领域第一代(单晶硅和多晶硅)、第二代(非晶硅和薄膜)和第三代(量子点、染料合成、聚合物和钙钛矿)材料发展的细分领域和突出特点,包括其优势和前景。