Efficient activation of peroxydisulfate by g-CN/BiMoO nanocomposite for enhanced organic pollutants degradation through non-radical dominated oxidation processes.

Persulfate-assisted photocatalysis technology is considered to be a promising method for the rapid and efficient degradation of organic pollutants in water environment remediation. In this study, a novel g-CN/BiMoO/PDS (CN/BMO/PDS) system is constructed and applied in 2,4-dinitrophenylhydrazine (2,4-DPH) degradation under visible light irradiation. Compared with the CN/BMO system, the degradation rate of 2,4-DPH is significantly improved from 59.7% to 90.2% within 60 min in the combined CN/BMO/PDS system. The enhanced performance can be attributed to the superior synergetic effects of CN/BMO, PDS and visible light irradiation. More importantly, singlet oxygen (O) is determined as the main reactive species based on the radical scavenging experiments and electron paramagnetic resonance (EPR), which indicates that the combined system can achieve non-radical oxidative degradation of pollutants, instead of the traditional radical oxidation process. In addition, the active sites of the reaction during the non-radical O oxidation are calculated by density functional theory (DFT), and the stability and reusability of catalyst are also investigated. In brief, the CN/BMO/PDS system has great application potential for removing organic pollutants from wastewater.