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恒电位和恒电流电解:有机电合成不同技术的介绍与比较

Constant Potential and Constant Current Electrolysis: An Introduction and Comparison of Different Techniques for Organic Electrosynthesis.

作者信息

Rafiee Mohammad, Mayer Mikayla N, Punchihewa Buwanila T, Mumau Matthew R

机构信息

Department of Chemistry, University of Missouri-Kansas City, 5009 Rockhill Road, Kansas City, Missouri 64110, United States.

出版信息

J Org Chem. 2021 Nov 19;86(22):15866-15874. doi: 10.1021/acs.joc.1c01391. Epub 2021 Sep 21.

DOI:10.1021/acs.joc.1c01391
PMID:34546751
Abstract

Electrosynthesis involves transferring charge between two electrodes to promote chemical reactions by applying potential. The modes of controlling the current and potential can affect the reaction mechanism, product distribution and yields, and add a control factor for reaction optimization. In this Synopsis, theoretical discussion is applied to specific case studies from the literature to illustrate methods of adjusting and tracking electrical parameters for the optimization and monitoring of electroorganic reactions.

摘要

电合成涉及通过施加电势在两个电极之间转移电荷以促进化学反应。控制电流和电势的模式会影响反应机理、产物分布和产率,并为反应优化增加一个控制因素。在本综述中,将理论讨论应用于文献中的具体案例研究,以说明调整和跟踪电参数以优化和监测有机电化学反应的方法。

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