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二维宏观X射线荧光光谱法揭示法国王后玛丽·安托瓦内特与瑞典伯爵阿克塞尔·冯·费尔森秘密通信的删节部分。

2D macro-XRF to reveal redacted sections of French queen Marie-Antoinette secret correspondence with Swedish count Axel von Fersen.

作者信息

Michelin Anne, Pottier Fabien, Andraud Christine

机构信息

Centre de Recherche sur la Conservation (CRC), MNHN, Sorbonne-Universités CNRS, MCC, USR 3224, CP21, 36 rue Geoffroy Saint Hilaire, 75005 Paris, France.

出版信息

Sci Adv. 2021 Oct;7(40):eabg4266. doi: 10.1126/sciadv.abg4266. Epub 2021 Oct 1.

DOI:10.1126/sciadv.abg4266
PMID:34597138
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10938494/
Abstract

During the French Revolution, Marie-Antoinette, queen of France and wife of Louis XVI, maintained a highly secret correspondence with the Swedish count Axel von Fersen, her close friend and rumored lover. An unidentified censor later redacted certain sections of the exchanged letters. This presumably sensitive content has been puzzling historians for almost 150 years. We report on the methodology that successfully unraveled this historical mystery. X-ray fluorescence spectroscopy was used in macroscanning mode on the redacted sections. Specific data processing was applied to improve the legibility of the hidden writings (elemental ratios, statistical data reduction, multimodal images fusion, unmixing procedure, and image treatments). This methodology successfully revealed the redacted contents of eight letters, shedding new light not only on Marie-Antoinette and Fersen relationship but also on the author of the redactions. It will also be of great interest for other historical and forensic cases involving the disentanglement of superimposed multi-elemental materials.

摘要

在法国大革命期间，法国王后玛丽 - 安托瓦内特（路易十六的妻子）与她的密友、传闻中的情人瑞典伯爵阿克塞尔·冯·费尔森保持着高度机密的通信。后来，一位身份不明的审查员对往来信件的某些部分进行了编辑。这些大概敏感的内容让历史学家们困惑了近150年。我们报告了成功解开这一历史谜团的方法。在编辑过的部分上以宏观扫描模式使用了X射线荧光光谱法。应用了特定的数据处理来提高隐藏文字的清晰度（元素比率、统计数据简化、多模态图像融合、解混程序和图像处理）。这种方法成功地揭示了八封信的编辑内容，不仅为玛丽 - 安托瓦内特和费尔森的关系，也为编辑者身份带来了新的线索。对于其他涉及解开叠加多元素材料纠缠的历史和法医案件来说，它也将具有极大的价值。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9599/10938494/9a08375aa898/sciadv.abg4266-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9599/10938494/60e9b4da234d/sciadv.abg4266-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9599/10938494/a3465b194794/sciadv.abg4266-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9599/10938494/63f4b5c04b68/sciadv.abg4266-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9599/10938494/a1150e6317e8/sciadv.abg4266-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9599/10938494/d38c0949695f/sciadv.abg4266-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9599/10938494/1b80566f5d64/sciadv.abg4266-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9599/10938494/f45a5e6a6f3a/sciadv.abg4266-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9599/10938494/3961772d301b/sciadv.abg4266-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9599/10938494/24232dd17deb/sciadv.abg4266-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9599/10938494/9a08375aa898/sciadv.abg4266-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9599/10938494/60e9b4da234d/sciadv.abg4266-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9599/10938494/a3465b194794/sciadv.abg4266-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9599/10938494/63f4b5c04b68/sciadv.abg4266-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9599/10938494/a1150e6317e8/sciadv.abg4266-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9599/10938494/d38c0949695f/sciadv.abg4266-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9599/10938494/1b80566f5d64/sciadv.abg4266-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9599/10938494/f45a5e6a6f3a/sciadv.abg4266-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9599/10938494/3961772d301b/sciadv.abg4266-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9599/10938494/24232dd17deb/sciadv.abg4266-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9599/10938494/9a08375aa898/sciadv.abg4266-f10.jpg

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